N -annulated perylene-based push-pull-type sensitizers

Handle URI:
http://hdl.handle.net/10754/564046
Title:
N -annulated perylene-based push-pull-type sensitizers
Authors:
Qi, Qingbiao; Wang, Xingzhu; Fan, Li; Zheng, Bin; Zeng, Wangdong; Luo, Jie; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Wang, Qing; Wu, Jishan
Abstract:
Alkoxy-wrapped N-annulated perylene (NP) was synthesized and used as a rigid and coplanar π-linker for three push-pull type metal-free sensitizers QB1-QB3. Their optical and electrochemical properties were tuned by varying the structure of acceptor. These new dyes were applied in Co(II)/(III) based dye-sensitized solar cells, and power conversion efficiency up to 6.95% was achieved, indicating that NP could be used as a new building block for the design of high-performance sensitizers in the future.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; HCL
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
6-Feb-2015
DOI:
10.1021/ol503749f
Type:
Article
ISSN:
15237060
Sponsors:
J.W. and Q.W. acknowledge financial support from MOE Tier 2 grant (MOE2011-T2-2-130), A*STAR-DST joint grant (IMRE/14-2C0239), and IMRE core funding (IMRE/13-1C0205). K.-W.H. acknowledges financial support from KAUST.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorQi, Qingbiaoen
dc.contributor.authorWang, Xingzhuen
dc.contributor.authorFan, Lien
dc.contributor.authorZheng, Binen
dc.contributor.authorZeng, Wangdongen
dc.contributor.authorLuo, Jieen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorWang, Qingen
dc.contributor.authorWu, Jishanen
dc.date.accessioned2015-08-03T12:29:42Zen
dc.date.available2015-08-03T12:29:42Zen
dc.date.issued2015-02-06en
dc.identifier.issn15237060en
dc.identifier.doi10.1021/ol503749fen
dc.identifier.urihttp://hdl.handle.net/10754/564046en
dc.description.abstractAlkoxy-wrapped N-annulated perylene (NP) was synthesized and used as a rigid and coplanar π-linker for three push-pull type metal-free sensitizers QB1-QB3. Their optical and electrochemical properties were tuned by varying the structure of acceptor. These new dyes were applied in Co(II)/(III) based dye-sensitized solar cells, and power conversion efficiency up to 6.95% was achieved, indicating that NP could be used as a new building block for the design of high-performance sensitizers in the future.en
dc.description.sponsorshipJ.W. and Q.W. acknowledge financial support from MOE Tier 2 grant (MOE2011-T2-2-130), A*STAR-DST joint grant (IMRE/14-2C0239), and IMRE core funding (IMRE/13-1C0205). K.-W.H. acknowledges financial support from KAUST.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleN -annulated perylene-based push-pull-type sensitizersen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentHCLen
dc.identifier.journalOrganic Lettersen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3Singapore, Singaporeen
dc.contributor.institutionDepartment of Materials Science and Engineering, NUSNNI-NanoCore, National University of Singapore, 9 Engineering Drive 1Singapore, Singaporeen
dc.contributor.institutionInstitute of Materials Research and Engineering, A STAR, 3 Research LinkSingapore, Singaporeen
kaust.authorZheng, Binen
kaust.authorHuang, Kuo-Weien
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