Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation

Handle URI:
http://hdl.handle.net/10754/564014
Title:
Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation
Authors:
Hassine, Ayoub; Bouhrara, Mohamed; Sebti, Said; Solhy, Abderrahim; Mahfouz, Remi ( 0000-0003-0981-0440 ) ; Luart, Denis; Lene, Christophe; Fihri, Aziz
Abstract:
This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Publisher:
Bentham Science Publishers Ltd.
Journal:
Current Organic Chemistry
Issue Date:
19-Jan-2015
DOI:
10.2174/1385272819666141117234222
Type:
Article
ISSN:
13852728
Sponsors:
We thank G. Santini for his support of this work and the Region Picardie for their financial support. The financial assistance of the Office Cherifien des Phosphates in the Moroccan Kingdom (OCP Group) towards this research is hereby acknowledged. This work was supported also by grant from the OCP Foundation.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorHassine, Ayouben
dc.contributor.authorBouhrara, Mohameden
dc.contributor.authorSebti, Saiden
dc.contributor.authorSolhy, Abderrahimen
dc.contributor.authorMahfouz, Remien
dc.contributor.authorLuart, Denisen
dc.contributor.authorLene, Christopheen
dc.contributor.authorFihri, Azizen
dc.date.accessioned2015-08-03T12:23:06Zen
dc.date.available2015-08-03T12:23:06Zen
dc.date.issued2015-01-19en
dc.identifier.issn13852728en
dc.identifier.doi10.2174/1385272819666141117234222en
dc.identifier.urihttp://hdl.handle.net/10754/564014en
dc.description.abstractThis report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.en
dc.description.sponsorshipWe thank G. Santini for his support of this work and the Region Picardie for their financial support. The financial assistance of the Office Cherifien des Phosphates in the Moroccan Kingdom (OCP Group) towards this research is hereby acknowledged. This work was supported also by grant from the OCP Foundation.en
dc.publisherBentham Science Publishers Ltd.en
dc.titleNatural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiationen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalCurrent Organic Chemistryen
dc.contributor.institutionLaboratoire de Chimie Organique Catalyse et Environnement, Université Hassan II Mohammedia- Casablanca, B.P. 7955Casablanca, Moroccoen
dc.contributor.institutionDepartment of Chemistry, School of Science and Technology, Nazarbayev UniversityAstana, Kazakhstanen
dc.contributor.institutionUniversité Mohammed VI Polytechnique, Lot 660-Hay Moulay RachidBen Guerir, Moroccoen
dc.contributor.institutionTransformations Intégrées de la Matière Renouvelable UTC/ESCOM, Centre de Recherche Royallieu, BP 20529Compiègne, Franceen
dc.contributor.institutionDepartment of Chemistry, University of HullHull, United Kingdomen
dc.contributor.institutionMAScIR Foundation, Rabat Design, Rue Mohamed El JazouliMadinat Al Irfane, Rabat, Moroccoen
kaust.authorMahfouz, Remien
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