Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane

Handle URI:
http://hdl.handle.net/10754/564007
Title:
Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane
Authors:
Hamzaoui, Bilel; El Eter, Mohamad; Abou-Hamad, Edy; Chen, Yin; Pelletier, Jeremie ( 0000-0002-4709-4898 ) ; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
The silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Solar and Photovoltaic Engineering Research Center (SPERC)
Publisher:
Wiley-Blackwell
Journal:
Chemistry - A European Journal
Issue Date:
13-Jan-2015
DOI:
10.1002/chem.201405788
Type:
Article
ISSN:
09476539
Sponsors:
The authors wish to thank the King Abdullah University of Science and Technology for continuous support.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorHamzaoui, Bilelen
dc.contributor.authorEl Eter, Mohamaden
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorChen, Yinen
dc.contributor.authorPelletier, Jeremieen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T12:22:50Zen
dc.date.available2015-08-03T12:22:50Zen
dc.date.issued2015-01-13en
dc.identifier.issn09476539en
dc.identifier.doi10.1002/chem.201405788en
dc.identifier.urihttp://hdl.handle.net/10754/564007en
dc.description.abstractThe silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.en
dc.description.sponsorshipThe authors wish to thank the King Abdullah University of Science and Technology for continuous support.en
dc.publisherWiley-Blackwellen
dc.subjectAzazirconacyclopropanesen
dc.subjectHydrogenationen
dc.subjectMonohydridesen
dc.subjectOrganometallic chemistryen
dc.subjectSurface chemistryen
dc.titleWell-defined single-site monohydride silica-supported zirconium from azazirconacyclopropaneen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.identifier.journalChemistry - A European Journalen
kaust.authorEl Eter, Mohamaden
kaust.authorAbou-Hamad, Edyen
kaust.authorChen, Yinen
kaust.authorPelletier, Jeremieen
kaust.authorBasset, Jean-Marieen
kaust.authorHamzaoui, Bilelen
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