From competition to cooperation: A highly efficient strategy towards well-defined (co)polypeptides

Handle URI:
http://hdl.handle.net/10754/563947
Title:
From competition to cooperation: A highly efficient strategy towards well-defined (co)polypeptides
Authors:
Zhao, Wei ( 0000-0001-7177-3180 ) ; Gnanou, Yves ( 0000-0001-6253-7856 ) ; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
By associating primary (slow but controlled ring-opening polymerization; ROP) and tertiary (fast but uncontrolled ROP) amines in the same molecule, a novel highly active organocatalytic system proceeding by an accelerated amine mechanism through monomer activation (AAMMA) and leading to living ROP of α-amino acid N-carboxyanhydrides at room temperature was successfully developed. This journal is
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Polymer Synthesis Laboratory; Chemical Science Program; KAUST Catalysis Center (KCC)
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
2015
DOI:
10.1039/c4cc09055a
Type:
Article
ISSN:
13597345
Sponsors:
This research was financially supported by King Abdullah University of Science and Technology.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorZhao, Weien
dc.contributor.authorGnanou, Yvesen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2015-08-03T12:20:31Zen
dc.date.available2015-08-03T12:20:31Zen
dc.date.issued2015en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c4cc09055aen
dc.identifier.urihttp://hdl.handle.net/10754/563947en
dc.description.abstractBy associating primary (slow but controlled ring-opening polymerization; ROP) and tertiary (fast but uncontrolled ROP) amines in the same molecule, a novel highly active organocatalytic system proceeding by an accelerated amine mechanism through monomer activation (AAMMA) and leading to living ROP of α-amino acid N-carboxyanhydrides at room temperature was successfully developed. This journal isen
dc.description.sponsorshipThis research was financially supported by King Abdullah University of Science and Technology.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleFrom competition to cooperation: A highly efficient strategy towards well-defined (co)polypeptidesen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentPolymer Synthesis Laboratoryen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalChem. Commun.en
kaust.authorZhao, Weien
kaust.authorGnanou, Yvesen
kaust.authorHadjichristidis, Nikolaosen
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