Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Handle URI:
http://hdl.handle.net/10754/563929
Title:
Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination
Authors:
So, Monica; Beyzavi, M. Hassan; Sawhney, Rohan; Shekhah, Osama ( 0000-0003-1861-9226 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Al-Juaid, Salih Salem; Hupp, Joseph T.; Farha, Omar K.
Abstract:
Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
2015
DOI:
10.1039/c4cc05727a
Type:
Article
ISSN:
13597345
Sponsors:
O.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorSo, Monicaen
dc.contributor.authorBeyzavi, M. Hassanen
dc.contributor.authorSawhney, Rohanen
dc.contributor.authorShekhah, Osamaen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorAl-Juaid, Salih Salemen
dc.contributor.authorHupp, Joseph T.en
dc.contributor.authorFarha, Omar K.en
dc.date.accessioned2015-08-03T12:19:53Zen
dc.date.available2015-08-03T12:19:53Zen
dc.date.issued2015en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c4cc05727aen
dc.identifier.urihttp://hdl.handle.net/10754/563929en
dc.description.abstractHerein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.en
dc.description.sponsorshipO.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titlePost-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordinationen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalChem. Commun.en
dc.contributor.institutionDepartment of Chemistry, Northwestern University, 2145 Sheridan RoadEvanston, IL, United Statesen
dc.contributor.institutionDepartment of Chemistry, King Abdulaziz UniversityJeddah, Saudi Arabiaen
kaust.authorShekhah, Osamaen
kaust.authorEddaoudi, Mohameden
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