Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

Handle URI:
http://hdl.handle.net/10754/563706
Title:
Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks
Authors:
Lu, Haisheng; Bai, Linlu; Xiong, Weiwei; Li, Peizhou; Ding, Junfeng; Zhang, Guodong; Wu, Tao ( 0000-0003-0845-4827 ) ; Zhao, Yanli; Lee, Jongmin; Yang, Yanhui; Geng, Baoyou; Zhang, Qichun
Abstract:
In this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; Solar and Photovoltaic Engineering Research Center (SPERC); Laboratory of Nano Oxides for Sustainable Energy
Publisher:
American Chemical Society (ACS)
Journal:
Inorganic Chemistry
Issue Date:
18-Aug-2014
DOI:
10.1021/ic5011133
Type:
Article
ISSN:
00201669
Sponsors:
The authors thank Prof. Tao Wu and Jian Lin for topology analysis. Q.Z. acknowledges AcRF Tier 1 (RG 16/12) and Tier 2 (ARC 2/13 and ARC 20/12) from MOE and the CREATE program (Nanomaterials for Energy and Water Management) from NRF Singapore. This work was also supported by the National Natural Science Foundation of China (Grant 21271009).
Is Supplemented By:
Lu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029958: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krgw; DOI:10.5517/cc13krgw; HANDLE:http://hdl.handle.net/10754/624377; Lu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029959: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krhx; DOI:10.5517/cc13krhx; HANDLE:http://hdl.handle.net/10754/624378; Lu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029960: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krjy; DOI:10.5517/cc13krjy; HANDLE:http://hdl.handle.net/10754/624379
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLu, Haishengen
dc.contributor.authorBai, Linluen
dc.contributor.authorXiong, Weiweien
dc.contributor.authorLi, Peizhouen
dc.contributor.authorDing, Junfengen
dc.contributor.authorZhang, Guodongen
dc.contributor.authorWu, Taoen
dc.contributor.authorZhao, Yanlien
dc.contributor.authorLee, Jongminen
dc.contributor.authorYang, Yanhuien
dc.contributor.authorGeng, Baoyouen
dc.contributor.authorZhang, Qichunen
dc.date.accessioned2015-08-03T12:07:09Zen
dc.date.available2015-08-03T12:07:09Zen
dc.date.issued2014-08-18en
dc.identifier.issn00201669en
dc.identifier.doi10.1021/ic5011133en
dc.identifier.urihttp://hdl.handle.net/10754/563706en
dc.description.abstractIn this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.en
dc.description.sponsorshipThe authors thank Prof. Tao Wu and Jian Lin for topology analysis. Q.Z. acknowledges AcRF Tier 1 (RG 16/12) and Tier 2 (ARC 2/13 and ARC 20/12) from MOE and the CREATE program (Nanomaterials for Energy and Water Management) from NRF Singapore. This work was also supported by the National Natural Science Foundation of China (Grant 21271009).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleSurfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworksen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentMaterials Science and Engineering Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.contributor.departmentLaboratory of Nano Oxides for Sustainable Energyen
dc.identifier.journalInorganic Chemistryen
dc.contributor.institutionKey Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Normal University, Wuhu 241000, Chinaen
dc.contributor.institutionSchool of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singaporeen
dc.contributor.institutionSchool of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 639798, Singaporeen
dc.contributor.institutionSchool of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singaporeen
kaust.authorDing, Junfengen
kaust.authorWu, Taoen
dc.relation.isSupplementedByLu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029958: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krgwen
dc.relation.isSupplementedByDOI:10.5517/cc13krgwen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624377en
dc.relation.isSupplementedByLu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029959: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krhxen
dc.relation.isSupplementedByDOI:10.5517/cc13krhxen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624378en
dc.relation.isSupplementedByLu, H.-S., Bai, L., Xiong, W.-W., Li, P., Ding, J., Zhang, G., … Zhang, Q. (2014). CCDC 1029960: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc13krjyen
dc.relation.isSupplementedByDOI:10.5517/cc13krjyen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624379en
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