Direct functionalization of nanodiamonds with maleimide

Handle URI:
http://hdl.handle.net/10754/563547
Title:
Direct functionalization of nanodiamonds with maleimide
Authors:
El Tall, Omar; Hou, Yuanfang ( 0000-0001-6508-8777 ) ; Abou-Hamad, Edy; Raja, Inam Ul haq; Hedhili, Mohamed N. ( 0000-0002-3624-036X ) ; Peng, Wei ( 0000-0002-7168-9795 ) ; Mahfouz, Remi ( 0000-0003-0981-0440 ) ; Bakr, Osman M. ( 0000-0002-3428-1002 ) ; Beaujuge, Pierre
Abstract:
Diamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Analytical Core Lab; Advanced Nanofabrication, Imaging and Characterization Core Lab; KAUST Catalysis Center (KCC); Materials Science and Engineering Program; Solar and Photovoltaic Engineering Research Center (SPERC); Core Labs; Chemical Science Program; Functional Nanomaterials Lab (FuNL)
Publisher:
American Chemical Society (ACS)
Journal:
Chemistry of Materials
Issue Date:
13-May-2014
DOI:
10.1021/cm500036x
Type:
Article
ISSN:
08974756
Sponsors:
The authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the "Competitive Research Grant" (CRG) program No. FIC/2010/02. The authors thank KAUST Analytical Core Laboratories for mass spectrometry and elemental analyses. OET thanks Dr. Clement Cabanetos for helpful discussions.
Appears in Collections:
Articles; Analytical Core Lab; Advanced Nanofabrication, Imaging and Characterization Core Lab; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Materials Science and Engineering Program; KAUST Catalysis Center (KCC); Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorEl Tall, Omaren
dc.contributor.authorHou, Yuanfangen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorRaja, Inam Ul haqen
dc.contributor.authorHedhili, Mohamed N.en
dc.contributor.authorPeng, Weien
dc.contributor.authorMahfouz, Remien
dc.contributor.authorBakr, Osman M.en
dc.contributor.authorBeaujuge, Pierreen
dc.date.accessioned2015-08-03T11:54:10Zen
dc.date.available2015-08-03T11:54:10Zen
dc.date.issued2014-05-13en
dc.identifier.issn08974756en
dc.identifier.doi10.1021/cm500036xen
dc.identifier.urihttp://hdl.handle.net/10754/563547en
dc.description.abstractDiamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.en
dc.description.sponsorshipThe authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the "Competitive Research Grant" (CRG) program No. FIC/2010/02. The authors thank KAUST Analytical Core Laboratories for mass spectrometry and elemental analyses. OET thanks Dr. Clement Cabanetos for helpful discussions.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleDirect functionalization of nanodiamonds with maleimideen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAnalytical Core Laben
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Laben
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentMaterials Science and Engineering Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.contributor.departmentCore Labsen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentFunctional Nanomaterials Lab (FuNL)en
dc.identifier.journalChemistry of Materialsen
kaust.authorEl Tall, Omaren
kaust.authorAbou-Hamad, Edyen
kaust.authorRaja, Inam Ul haqen
kaust.authorHedhili, Mohamed N.en
kaust.authorMahfouz, Remien
kaust.authorBakr, Osman M.en
kaust.authorBeaujuge, Pierreen
kaust.authorHou, Yuanfangen
kaust.authorPeng, Weien
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