4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes

Handle URI:
http://hdl.handle.net/10754/563539
Title:
4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodes
Authors:
Schoedel, Alexander; Jaquier, Michael; Boyette, Wesley; Wojtas, Łukasz; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Zaworotko, Michael J.
Abstract:
A two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.
KAUST Department:
Chemical Science Program; Physical Sciences and Engineering (PSE) Division; Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society (ACS)
Journal:
Crystal Growth & Design
Issue Date:
7-May-2014
DOI:
10.1021/cg500205f
Type:
Article
ISSN:
15287483
Sponsors:
This work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).
Is Supplemented By:
Schoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010338: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xbkw; DOI:10.5517/cc12xbkw; HANDLE:http://hdl.handle.net/10754/624342; Schoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010339: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xblx; DOI:10.5517/cc12xblx; HANDLE:http://hdl.handle.net/10754/624343
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorSchoedel, Alexanderen
dc.contributor.authorJaquier, Michaelen
dc.contributor.authorBoyette, Wesleyen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorZaworotko, Michael J.en
dc.date.accessioned2015-08-03T11:53:58Zen
dc.date.available2015-08-03T11:53:58Zen
dc.date.issued2014-05-07en
dc.identifier.issn15287483en
dc.identifier.doi10.1021/cg500205fen
dc.identifier.urihttp://hdl.handle.net/10754/563539en
dc.description.abstractA two-step crystal engineering strategy has been utilized to synthesize a new and versatile class of metal-organic materials, the first to exhibit 4,6-connected fsb topology. The new fsb networks are constructed from simple and inexpensive nodes (4-connected Zn(CO2)(py)2 tetrahedra; 6-connected Cr(μ3-O)(RCO2)6 trigonal prisms) and linker ligands (isonicotinate and various dicarboxylates). Further, since interpenetration is precluded, they can exhibit extra-large void volumes. These fsb nets are prototypal for what should ultimately become a large family of related structures given the ready availability of functionalized and/or expanded variants of both linker ligands. The fsb nets described herein therefore represent platforms or blueprints for a new family of ultrahigh surface area porous materials. © 2014 American Chemical Society.en
dc.description.sponsorshipThis work was partially supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Society (ACS)en
dc.title4,6-connected fsb topology networks obtained through two-step crystal engineering of decorated trigonal prismatic nodesen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalCrystal Growth & Designen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United Statesen
dc.contributor.institutionDepartment of Chemical and Environmental Science, University of Limerick, Limerick, Irelanden
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedBySchoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010338: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xbkwen
dc.relation.isSupplementedByDOI:10.5517/cc12xbkwen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624342en
dc.relation.isSupplementedBySchoedel, A., Jaquier, M., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2014). CCDC 1010339: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12xblxen
dc.relation.isSupplementedByDOI:10.5517/cc12xblxen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624343en
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