Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

Handle URI:
http://hdl.handle.net/10754/563387
Title:
Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis
Authors:
Luebke, Ryan ( 0000-0002-1285-3321 ) ; Weselinski, Lukasz Jan ( 0000-0003-4516-2727 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Chen, Zhijie; Wojtas, Łukasz; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Advanced Membranes and Porous Materials Research Center
Publisher:
American Chemical Society (ACS)
Journal:
Crystal Growth & Design
Issue Date:
5-Feb-2014
DOI:
10.1021/cg401802s
Type:
Article
ISSN:
15287483
Sponsors:
Authors gratefully acknowledge KAUST for funding.
Is Supplemented By:
Luebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). CCDC 974613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11q542; DOI:10.5517/cc11q542; HANDLE:http://hdl.handle.net/10754/624294
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorLuebke, Ryanen
dc.contributor.authorWeselinski, Lukasz Janen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorChen, Zhijieen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2015-08-03T11:47:18Zen
dc.date.available2015-08-03T11:47:18Zen
dc.date.issued2014-02-05en
dc.identifier.issn15287483en
dc.identifier.doi10.1021/cg401802sen
dc.identifier.urihttp://hdl.handle.net/10754/563387en
dc.description.abstractHere we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.en
dc.description.sponsorshipAuthors gratefully acknowledge KAUST for funding.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleMicroporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysisen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.identifier.journalCrystal Growth & Designen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620, United Statesen
kaust.authorLuebke, Ryanen
kaust.authorWeselinski, Lukasz Janen
kaust.authorBelmabkhout, Youssefen
kaust.authorEddaoudi, Mohameden
kaust.authorChen, Zhijieen
dc.relation.isSupplementedByLuebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). CCDC 974613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11q542en
dc.relation.isSupplementedByDOI:10.5517/cc11q542en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624294en
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.