A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework

Handle URI:
http://hdl.handle.net/10754/563252
Title:
A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework
Authors:
Pham, Tony T.; Forrest, Katherine A.; Georgiev, Peter A L; Lohstroh, Wiebke; Xue, Dongxu; Hogan, Adam; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Space, Brian; Eckert, Juergen
Abstract:
A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption. This journal is
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
2014
DOI:
10.1039/c4cc05987e
Type:
Article
ISSN:
13597345
Sponsors:
B.S. acknowledges the National Science Foundation (Award No. CHE-1152362), the computational resources that were made available by a XSEDE Grant (No. TG-DMR090028), and the use of the services provided by Research Computing at the University of South Florida. This work is based in part on experiments performed on the TOFTOF instrument operated by FRM-II at the Heinz Maier-Leibnitz Zentrum (MLZ), Garching, Germany. P.A.G. acknowledges support from the Project "Beyond Everest'' under EU programme REGPOT-2011-1. This research project was also supported by the European Commission under the 7th Framework Programme through the 'Research Infrastructures' action of the 'Capacities' Programme, NMI3-II Grant No. 283883. The synthesis of the MOF studied herein and the attendant inelastic neutron scattering (INS) studies were supported by King Abdullah University of Science and Technology (KAUST).
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorPham, Tony T.en
dc.contributor.authorForrest, Katherine A.en
dc.contributor.authorGeorgiev, Peter A Len
dc.contributor.authorLohstroh, Wiebkeen
dc.contributor.authorXue, Dongxuen
dc.contributor.authorHogan, Adamen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorSpace, Brianen
dc.contributor.authorEckert, Juergenen
dc.date.accessioned2015-08-03T11:44:09Zen
dc.date.available2015-08-03T11:44:09Zen
dc.date.issued2014en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c4cc05987een
dc.identifier.urihttp://hdl.handle.net/10754/563252en
dc.description.abstractA combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption. This journal isen
dc.description.sponsorshipB.S. acknowledges the National Science Foundation (Award No. CHE-1152362), the computational resources that were made available by a XSEDE Grant (No. TG-DMR090028), and the use of the services provided by Research Computing at the University of South Florida. This work is based in part on experiments performed on the TOFTOF instrument operated by FRM-II at the Heinz Maier-Leibnitz Zentrum (MLZ), Garching, Germany. P.A.G. acknowledges support from the Project "Beyond Everest'' under EU programme REGPOT-2011-1. This research project was also supported by the European Commission under the 7th Framework Programme through the 'Research Infrastructures' action of the 'Capacities' Programme, NMI3-II Grant No. 283883. The synthesis of the MOF studied herein and the attendant inelastic neutron scattering (INS) studies were supported by King Abdullah University of Science and Technology (KAUST).en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleA high rotational barrier for physisorbed hydrogen in an fcu-metal-organic frameworken
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalChem. Commun.en
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue CHE205Tampa, FL, United Statesen
dc.contributor.institutionDepartment of Structural Chemistry, University of Milan, 21 Via G. VenezianMilan, Italyen
dc.contributor.institutionFaculty of Chemistry and Pharmacy, University of Sofia, 1 James Bourchier Blvd.Sofia, Bulgariaen
dc.contributor.institutionHeinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, Lichtenbergstraße1Garching, Germanyen
kaust.authorXue, Dongxuen
kaust.authorEddaoudi, Mohameden
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