Well-defined mono(η3-allyl)nickel complex MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina: A molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Handle URI:
http://hdl.handle.net/10754/563214
Title:
Well-defined mono(η3-allyl)nickel complex MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina: A molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles
Authors:
Li, Lidong; Abou-Hamad, Edy; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Emsley, Lyndon; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1-3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η3-allyl)nickel complexes MONi(η 3-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR. © 2014 the Partner Organisations.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Core Labs
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chemical Communications
Issue Date:
2014
DOI:
10.1039/c4cc02962c
Type:
Article
ISSN:
13597345
Sponsors:
We gratefully appreciate Saudi Basic Industries Corporation (SABIC) for financial support.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLi, Lidongen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorAnjum, Dalaver H.en
dc.contributor.authorZhou, Luen
dc.contributor.authorLaveille, Pacoen
dc.contributor.authorEmsley, Lyndonen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T11:38:18Zen
dc.date.available2015-08-03T11:38:18Zen
dc.date.issued2014en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c4cc02962cen
dc.identifier.urihttp://hdl.handle.net/10754/563214en
dc.description.abstractPreparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1-3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η3-allyl)nickel complexes MONi(η 3-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR. © 2014 the Partner Organisations.en
dc.description.sponsorshipWe gratefully appreciate Saudi Basic Industries Corporation (SABIC) for financial support.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleWell-defined mono(η3-allyl)nickel complex MONi(η3-C3H5) (M = Si or Al) grafted onto silica or alumina: A molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticlesen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentCore Labsen
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionUniversité de Lyon, CNRS/ENS-Lyon/UCB Lyon 1, Centre de RMN À Très Hauts Champs, 5 rue de la Doua, 69100 Villeurbanne, Franceen
kaust.authorLi, Lidongen
kaust.authorAbou-Hamad, Edyen
kaust.authorAnjum, Dalaver H.en
kaust.authorZhou, Luen
kaust.authorLaveille, Pacoen
kaust.authorBasset, Jean-Marieen
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