From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Handle URI:
http://hdl.handle.net/10754/563176
Title:
From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis
Authors:
Manzini, Simone; Nelson, David J.; Lébl, Tomáš; Poater, Albert; Cavallo, Luigi ( 0000-0002-1398-338X ) ; Slawin, Alexandra M. Z.; Nolan, Steven P.
Abstract:
The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chemical Communications
Issue Date:
2014
DOI:
10.1039/c3cc49481k
Type:
Article
ISSN:
13597345
Sponsors:
Research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no. CP-FP 211468-2 EUMET. SPN thanks the ERC for Advanced Investigator Award 'FUNCAT'. SPN is a Royal Society Wolfson Research Merit Award holder. LC thanks BSC (QCM-2010-2-0020), and the HPC team of Enea for using the ENEA-GRID and the HPC facilities CRESCO in Portici (Italy) for access to remarkable computational resources. AP thanks the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170) and Generalitat de Catalunya for a BE-DGR fellowship. We thank Umicore for gifts of materials and ligands.
Is Supplemented By:
Manzini, S., Nelson, D. J., Lebl, T., Poater, A., Cavallo, L., Slawin, A. M. Z., & Nolan, S. P. (2014). CCDC 976892: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11sjn0; DOI:10.5517/cc11sjn0; HANDLE:http://hdl.handle.net/10754/624295
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorManzini, Simoneen
dc.contributor.authorNelson, David J.en
dc.contributor.authorLébl, Tomášen
dc.contributor.authorPoater, Alberten
dc.contributor.authorCavallo, Luigien
dc.contributor.authorSlawin, Alexandra M. Z.en
dc.contributor.authorNolan, Steven P.en
dc.date.accessioned2015-08-03T11:37:31Zen
dc.date.available2015-08-03T11:37:31Zen
dc.date.issued2014en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c3cc49481ken
dc.identifier.urihttp://hdl.handle.net/10754/563176en
dc.description.abstractThe synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.en
dc.description.sponsorshipResearch leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no. CP-FP 211468-2 EUMET. SPN thanks the ERC for Advanced Investigator Award 'FUNCAT'. SPN is a Royal Society Wolfson Research Merit Award holder. LC thanks BSC (QCM-2010-2-0020), and the HPC team of Enea for using the ENEA-GRID and the HPC facilities CRESCO in Portici (Italy) for access to remarkable computational resources. AP thanks the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170) and Generalitat de Catalunya for a BE-DGR fellowship. We thank Umicore for gifts of materials and ligands.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleFrom ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysisen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionEaStCHEM School of Chemistry, University of St Andrews, North Haugh, St-Andrews Fife-KY16 9ST, United Kingdomen
dc.contributor.institutionCatalan Institute for Water Research (ICRA), Scientific and Technological Park of the University of Girona, H2O Building, Emili Grahit 101, E-17003 Girona, Spainen
dc.contributor.institutionDepartment of Chemistry and Biology, University of Salerno, Via Ponte don Melillo, Fisciano I-84084, Italyen
kaust.authorCavallo, Luigien
dc.relation.isSupplementedByManzini, S., Nelson, D. J., Lebl, T., Poater, A., Cavallo, L., Slawin, A. M. Z., & Nolan, S. P. (2014). CCDC 976892: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11sjn0en
dc.relation.isSupplementedByDOI:10.5517/cc11sjn0en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624295en
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.