Insitu synthesis of self-assembled gold nanoparticles on glass or silicon substrates through reactive inkjet printing

Handle URI:
http://hdl.handle.net/10754/563153
Title:
Insitu synthesis of self-assembled gold nanoparticles on glass or silicon substrates through reactive inkjet printing
Authors:
Abulikemu, Mutalifu ( 0000-0002-3366-4239 ) ; Da'As, Eman Husni; Haverinen, Hanna M.; Cha, Dong Kyu; Malik, Mohammad A.; Jabbour, Ghassan Elie
Abstract:
A facile and low cost method for the synthesis of self-assembled nanoparticles (NPs) with minimal size variation and chemical waste by using reactive inkjet printing was developed. Gold NPs with diameters as small as (8±2)nm can be made at low temperature (120 °C). The size of the resulting NPs can be readily controlled through the concentration of the gold precursor and oleylamine ink. The pure gold composition of the synthesized NPs was confirmed by energy-dispersive X-ray spectroscopy (EDXS) analysis. High-resolution SEM (HRSEM) and TEM (HRTEM), and X-ray diffraction revealed their size and face-centered cubic (fcc) crystal structure, respectively. Owing to the high density of the NP film, UV/Vis spectroscopy showed a red shift in the intrinsic plasmonic resonance peak. We envision the extension of this approach to the synthesis of other nanomaterials and the production of tailored functional nanomaterials and devices. Midas touch: The use of low-cost manufacturing approaches in the synthesis of nanoparticles is critical for many applications. Reactive inkjet printing, along with a judicious choice of precursor/solvent system, was used to synthesize a relatively uniform assembly of crystalline gold nanoparticles, with diameters as small as (8±2)nm, over a given substrate surface. © 2014 WILEY-VCH Verlag GmbH.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; Imaging and Characterization Core Lab; KAUST Solar Center (KSC); Advanced Nanofabrication, Imaging and Characterization Core Lab; Core Labs
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
18-Dec-2013
DOI:
10.1002/anie.201308429
Type:
Article
ISSN:
14337851
Appears in Collections:
Articles; Advanced Nanofabrication, Imaging and Characterization Core Lab; Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; KAUST Solar Center (KSC)

Full metadata record

DC FieldValue Language
dc.contributor.authorAbulikemu, Mutalifuen
dc.contributor.authorDa'As, Eman Husnien
dc.contributor.authorHaverinen, Hanna M.en
dc.contributor.authorCha, Dong Kyuen
dc.contributor.authorMalik, Mohammad A.en
dc.contributor.authorJabbour, Ghassan Elieen
dc.date.accessioned2015-08-03T11:37:01Zen
dc.date.available2015-08-03T11:37:01Zen
dc.date.issued2013-12-18en
dc.identifier.issn14337851en
dc.identifier.doi10.1002/anie.201308429en
dc.identifier.urihttp://hdl.handle.net/10754/563153en
dc.description.abstractA facile and low cost method for the synthesis of self-assembled nanoparticles (NPs) with minimal size variation and chemical waste by using reactive inkjet printing was developed. Gold NPs with diameters as small as (8±2)nm can be made at low temperature (120 °C). The size of the resulting NPs can be readily controlled through the concentration of the gold precursor and oleylamine ink. The pure gold composition of the synthesized NPs was confirmed by energy-dispersive X-ray spectroscopy (EDXS) analysis. High-resolution SEM (HRSEM) and TEM (HRTEM), and X-ray diffraction revealed their size and face-centered cubic (fcc) crystal structure, respectively. Owing to the high density of the NP film, UV/Vis spectroscopy showed a red shift in the intrinsic plasmonic resonance peak. We envision the extension of this approach to the synthesis of other nanomaterials and the production of tailored functional nanomaterials and devices. Midas touch: The use of low-cost manufacturing approaches in the synthesis of nanoparticles is critical for many applications. Reactive inkjet printing, along with a judicious choice of precursor/solvent system, was used to synthesize a relatively uniform assembly of crystalline gold nanoparticles, with diameters as small as (8±2)nm, over a given substrate surface. © 2014 WILEY-VCH Verlag GmbH.en
dc.publisherWiley-Blackwellen
dc.subjectgolden
dc.subjectinkjet printingen
dc.subjectinsitu synthesisen
dc.subjectnanofabricationen
dc.subjectnanoparticlesen
dc.titleInsitu synthesis of self-assembled gold nanoparticles on glass or silicon substrates through reactive inkjet printingen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentMaterials Science and Engineering Programen
dc.contributor.departmentImaging and Characterization Core Laben
dc.contributor.departmentKAUST Solar Center (KSC)en
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Laben
dc.contributor.departmentCore Labsen
dc.identifier.journalAngewandte Chemie International Editionen
dc.contributor.institutionSchool of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, United Kingdomen
dc.contributor.institutionRenewable Energy Center, University of Nevada, 038 Laxalt Mining Research (LMR), Reno, NV 89557, United Statesen
kaust.authorAbulikemu, Mutalifuen
kaust.authorCha, Dong Kyuen
kaust.authorJabbour, Ghassan Elieen
kaust.authorDa'As, Eman Husnien
kaust.authorHaverinen, Hanna M.en
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