[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

Handle URI:
http://hdl.handle.net/10754/563064
Title:
[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface
Authors:
Chen, Yin; Callens, Emmanuel; Abou-Hamad, Edy; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Solar and Photovoltaic Engineering Research Center (SPERC)
Publisher:
Elsevier BV
Journal:
Journal of Organometallic Chemistry
Issue Date:
Nov-2013
DOI:
10.1016/j.jorganchem.2013.04.050
Type:
Article
ISSN:
0022328X
Sponsors:
We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Yinen
dc.contributor.authorCallens, Emmanuelen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T11:34:57Zen
dc.date.available2015-08-03T11:34:57Zen
dc.date.issued2013-11en
dc.identifier.issn0022328Xen
dc.identifier.doi10.1016/j.jorganchem.2013.04.050en
dc.identifier.urihttp://hdl.handle.net/10754/563064en
dc.description.abstractA novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipWe thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.en
dc.publisherElsevier BVen
dc.subject&alpha-Hydrogen abstractionen
dc.subjectKineticsen
dc.subjectSurface organometallics chemistryen
dc.subjectSurface tantalum methylideneen
dc.title[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surfaceen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.identifier.journalJournal of Organometallic Chemistryen
kaust.authorChen, Yinen
kaust.authorCallens, Emmanuelen
kaust.authorAbou-Hamad, Edyen
kaust.authorBasset, Jean-Marieen
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