Technique for rapid detection of phthalates in water and beverages

Handle URI:
http://hdl.handle.net/10754/562751
Title:
Technique for rapid detection of phthalates in water and beverages
Authors:
Zia, Asif I.; Rahman, Mohammed Syaifudin Abdul; Mukhopadhyay, Subhas Chandra; Yu, Paklam; Al-Bahadly, Ibrahim H.; Gooneratne, Chinthaka Pasan; Kosel, Jürgen ( 0000-0002-8998-8275 ) ; Liao, Taishan
Abstract:
The teratogenic and carcinogenic effects of phthalate esters on living beings are proven in toxicology studies. These ubiquitous food and environmental pollutants pose a great danger to the human race due to their extraordinary use as a plasticizer in the consumer product industry. Contemporary detection techniques used for phthalates require a high level of skills, expensive equipment and longer analysis time than the presented technique. Presented research work introduces a real time non-invasive detection technique using a new type of silicon substrate based planar interdigital (ID) sensor fabricated on basis of thin film micro-electromechanical system (MEMS) semiconductor device fabrication technology. Electrochemical impedance spectroscopy (EIS) was used in conjunction with the fabricated sensor to detect phthalates in deionized water. Various concentrations of di(2-ethylhexyl) phthalate (DEHP) as low as 2 ppb to a higher level of 2 ppm in deionized water were detected distinctively using new planar ID sensor based EIS sensing system. Dip testing method was used to obtain the conductance and dielectric properties of the bulk samples. Parylene C polymer coating was used as a passivation layer on the surface of the fabricated sensor to reduce the influence of Faradaic currents. In addition, inherent dielectric properties of the coating enhanced the sensitivity of the capacitive type sensor. Electrochemical spectrum analysis algorithm was used to model experimentally observed impedance spectrum to deduce constant phase element (CPE) equivalent circuit to analyse the kinetic processes taking place inside the electrochemical cell. Curve fitting technique was used to extract the values of the circuit components and explain experimental results on theoretical grounds. The sensor performance was tested by adding DEHP to an energy drink at concentrations above and below the minimal risk level (MRL) limit set by the ATSDR (Agency for Toxic Substances & Disease Registry), USA. Results showed that the new sensor was able to detect different concentrations of phthalates in energy drinks. The experimental outcomes provided sufficient indication to favour the development of a low cost detection system for rapid quantification of phthalates in beverages for industrial use. © 2012 Elsevier Ltd. All rights reserved.
KAUST Department:
Sensing, Magnetism and Microsystems Lab; Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division; Electrical Engineering Program
Publisher:
Elsevier
Journal:
Journal of Food Engineering
Issue Date:
May-2013
DOI:
10.1016/j.jfoodeng.2012.12.024
Type:
Article
ISSN:
02608774
Sponsors:
The authors would like to thank Massey University, New Zealand, for providing the best possible research facilities. The authors are obliged to COMSATS Institute of Information Technology and Higher Education Commission Pakistan, for providing support and funds to work on this project. Special thanks to all researches referenced throughout the paper whose valuable research has guided the way through to this research work, and to all whom. that had fruitful discussions and collaborations with the authors.
Appears in Collections:
Articles; Electrical Engineering Program; Sensing, Magnetism and Microsystems Lab; Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorZia, Asif I.en
dc.contributor.authorRahman, Mohammed Syaifudin Abdulen
dc.contributor.authorMukhopadhyay, Subhas Chandraen
dc.contributor.authorYu, Paklamen
dc.contributor.authorAl-Bahadly, Ibrahim H.en
dc.contributor.authorGooneratne, Chinthaka Pasanen
dc.contributor.authorKosel, Jürgenen
dc.contributor.authorLiao, Taishanen
dc.date.accessioned2015-08-03T11:04:21Zen
dc.date.available2015-08-03T11:04:21Zen
dc.date.issued2013-05en
dc.identifier.issn02608774en
dc.identifier.doi10.1016/j.jfoodeng.2012.12.024en
dc.identifier.urihttp://hdl.handle.net/10754/562751en
dc.description.abstractThe teratogenic and carcinogenic effects of phthalate esters on living beings are proven in toxicology studies. These ubiquitous food and environmental pollutants pose a great danger to the human race due to their extraordinary use as a plasticizer in the consumer product industry. Contemporary detection techniques used for phthalates require a high level of skills, expensive equipment and longer analysis time than the presented technique. Presented research work introduces a real time non-invasive detection technique using a new type of silicon substrate based planar interdigital (ID) sensor fabricated on basis of thin film micro-electromechanical system (MEMS) semiconductor device fabrication technology. Electrochemical impedance spectroscopy (EIS) was used in conjunction with the fabricated sensor to detect phthalates in deionized water. Various concentrations of di(2-ethylhexyl) phthalate (DEHP) as low as 2 ppb to a higher level of 2 ppm in deionized water were detected distinctively using new planar ID sensor based EIS sensing system. Dip testing method was used to obtain the conductance and dielectric properties of the bulk samples. Parylene C polymer coating was used as a passivation layer on the surface of the fabricated sensor to reduce the influence of Faradaic currents. In addition, inherent dielectric properties of the coating enhanced the sensitivity of the capacitive type sensor. Electrochemical spectrum analysis algorithm was used to model experimentally observed impedance spectrum to deduce constant phase element (CPE) equivalent circuit to analyse the kinetic processes taking place inside the electrochemical cell. Curve fitting technique was used to extract the values of the circuit components and explain experimental results on theoretical grounds. The sensor performance was tested by adding DEHP to an energy drink at concentrations above and below the minimal risk level (MRL) limit set by the ATSDR (Agency for Toxic Substances & Disease Registry), USA. Results showed that the new sensor was able to detect different concentrations of phthalates in energy drinks. The experimental outcomes provided sufficient indication to favour the development of a low cost detection system for rapid quantification of phthalates in beverages for industrial use. © 2012 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipThe authors would like to thank Massey University, New Zealand, for providing the best possible research facilities. The authors are obliged to COMSATS Institute of Information Technology and Higher Education Commission Pakistan, for providing support and funds to work on this project. Special thanks to all researches referenced throughout the paper whose valuable research has guided the way through to this research work, and to all whom. that had fruitful discussions and collaborations with the authors.en
dc.publisherElsevieren
dc.subjectConstant phase elementen
dc.subjectDEHPen
dc.subjectElectrochemicalen
dc.subjectImpedance spectroscopyen
dc.subjectInterdigital sensorsen
dc.subjectPhthalatesen
dc.titleTechnique for rapid detection of phthalates in water and beveragesen
dc.typeArticleen
dc.contributor.departmentSensing, Magnetism and Microsystems Laben
dc.contributor.departmentComputer, Electrical and Mathematical Sciences and Engineering (CEMSE) Divisionen
dc.contributor.departmentElectrical Engineering Programen
dc.identifier.journalJournal of Food Engineeringen
dc.contributor.institutionSchool of Engineering and Advanced Technology, Massey University, Palmerston North, New Zealanden
dc.contributor.institutionInstrument Technology Research Centre, National Applied Research Laboratories, Hsinchu, Taiwanen
dc.contributor.institutionDepartment of Physics, COMSATS Institute of Information Technology, Islamabad, Pakistanen
kaust.authorGooneratne, Chinthaka Pasanen
kaust.authorKosel, Jürgenen
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