Stepwise transformation of the molecular building blocks in a porphyrin-encapsulating metal-organic material

Handle URI:
http://hdl.handle.net/10754/562727
Title:
Stepwise transformation of the molecular building blocks in a porphyrin-encapsulating metal-organic material
Authors:
Zhang, ZhenJie; Wojtas, Łukasz; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Zaworotko, Michael J.
Abstract:
When immersed in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4]·[Cd(C 44H36N8)(S)]·[S], BPT = biphenyl-3,4′,5-tricarboxylate) undergoes a transformation of its [Cd 2(COO)6]2- molecular building blocks (MBBs) into novel tetranuclear [Cu4X2(COO)6(S) 2] MBBs to form P11-Cu. The transformation occurs in single-crystal to single-crystal fashion, and its stepwise mechanism was studied by varying the Cd2+/Cu2+ ratio of the solution in which crystals of P11 were immersed. P11-16/1 (Cd in framework retained, Cd in encapsulated porphyrins exchanged) and other intermediate phases were thereby isolated and structurally characterized. P11-16/1 and P11-Cu retain the microporosity of P11, and the relatively larger MBBs in P11-Cu permit a 20% unit cell expansion and afford a higher surface area and a larger pore size. © 2013 American Chemical Society.
KAUST Department:
Chemical Science Program; Physical Sciences and Engineering (PSE) Division; Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society
Journal:
Journal of the American Chemical Society
Issue Date:
24-Apr-2013
DOI:
10.1021/ja4015666
Type:
Article
ISSN:
00027863
Sponsors:
This work was supported by Award FIC/2010/06 from King Abdullah University of Science and Technology. The data for P11-Cu were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation/Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.
Is Supplemented By:
Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954550: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118y9; DOI:10.5517/cc1118y9; HANDLE:http://hdl.handle.net/10754/624248; Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954551: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118zb; DOI:10.5517/cc1118zb; HANDLE:http://hdl.handle.net/10754/624249; Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954552: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11190d; DOI:10.5517/cc11190d; HANDLE:http://hdl.handle.net/10754/624250; Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r; DOI:10.5517/ccyh73r; HANDLE:http://hdl.handle.net/10754/624704
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorZhang, ZhenJieen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorZaworotko, Michael J.en
dc.date.accessioned2015-08-03T11:03:26Zen
dc.date.available2015-08-03T11:03:26Zen
dc.date.issued2013-04-24en
dc.identifier.issn00027863en
dc.identifier.doi10.1021/ja4015666en
dc.identifier.urihttp://hdl.handle.net/10754/562727en
dc.description.abstractWhen immersed in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4]·[Cd(C 44H36N8)(S)]·[S], BPT = biphenyl-3,4′,5-tricarboxylate) undergoes a transformation of its [Cd 2(COO)6]2- molecular building blocks (MBBs) into novel tetranuclear [Cu4X2(COO)6(S) 2] MBBs to form P11-Cu. The transformation occurs in single-crystal to single-crystal fashion, and its stepwise mechanism was studied by varying the Cd2+/Cu2+ ratio of the solution in which crystals of P11 were immersed. P11-16/1 (Cd in framework retained, Cd in encapsulated porphyrins exchanged) and other intermediate phases were thereby isolated and structurally characterized. P11-16/1 and P11-Cu retain the microporosity of P11, and the relatively larger MBBs in P11-Cu permit a 20% unit cell expansion and afford a higher surface area and a larger pore size. © 2013 American Chemical Society.en
dc.description.sponsorshipThis work was supported by Award FIC/2010/06 from King Abdullah University of Science and Technology. The data for P11-Cu were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation/Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.en
dc.publisherAmerican Chemical Societyen
dc.titleStepwise transformation of the molecular building blocks in a porphyrin-encapsulating metal-organic materialen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United Statesen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954550: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118y9en
dc.relation.isSupplementedByDOI:10.5517/cc1118y9en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624248en
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954551: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118zben
dc.relation.isSupplementedByDOI:10.5517/cc1118zben
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624249en
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954552: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11190den
dc.relation.isSupplementedByDOI:10.5517/cc11190den
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624250en
dc.relation.isSupplementedByZhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73ren
dc.relation.isSupplementedByDOI:10.5517/ccyh73ren
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624704en
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