Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent

Handle URI:
http://hdl.handle.net/10754/562672
Title:
Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent
Authors:
Lin, Xiaoxi; Wang, Guimei; Li, Huaifeng ( 0000-0001-9661-803X ) ; Huang, Yuanyuan; He, Weiming; Ye, Dandan; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Yuan, Yaofeng; Weng, Zhiqiang
Abstract:
A copper-catalyzed method for the trifluoromethylation of arylsulfinates with Togni's reagent has been developed, affording aryltrifluoromethylsulfones in moderate to good yields. A wide range of functional groups in arylsulfinates are compatible with the reaction conditions. © 2013 Elsevier Ltd. All rights reserved.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; HCL
Publisher:
Elsevier
Journal:
Tetrahedron
Issue Date:
Mar-2013
DOI:
10.1016/j.tet.2013.01.041
Type:
Article
ISSN:
00404020
Sponsors:
We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W.H.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLin, Xiaoxien
dc.contributor.authorWang, Guimeien
dc.contributor.authorLi, Huaifengen
dc.contributor.authorHuang, Yuanyuanen
dc.contributor.authorHe, Weimingen
dc.contributor.authorYe, Dandanen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorYuan, Yaofengen
dc.contributor.authorWeng, Zhiqiangen
dc.date.accessioned2015-08-03T11:00:47Zen
dc.date.available2015-08-03T11:00:47Zen
dc.date.issued2013-03en
dc.identifier.issn00404020en
dc.identifier.doi10.1016/j.tet.2013.01.041en
dc.identifier.urihttp://hdl.handle.net/10754/562672en
dc.description.abstractA copper-catalyzed method for the trifluoromethylation of arylsulfinates with Togni's reagent has been developed, affording aryltrifluoromethylsulfones in moderate to good yields. A wide range of functional groups in arylsulfinates are compatible with the reaction conditions. © 2013 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipWe acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W.H.en
dc.publisherElsevieren
dc.subjectAryltrifluoromethylsulphonesen
dc.subjectCopper catalysten
dc.subjectElectrophilic trifluoromethylation reactionen
dc.titleCopper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagenten
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentHCLen
dc.identifier.journalTetrahedronen
dc.contributor.institutionDepartment of Chemistry, Fuzhou University, Fujian 350108, Chinaen
dc.contributor.institutionState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, Chinaen
kaust.authorLi, Huaifengen
kaust.authorHuang, Kuo-Weien
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