Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Handle URI:
http://hdl.handle.net/10754/562557
Title:
Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation
Authors:
El Eter, Mohamad; Hamzaoui, Bilel; Abou-Hamad, Edy; Pelletier, Jeremie ( 0000-0002-4709-4898 ) ; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Issue Date:
2013
DOI:
10.1039/c3cc40385h
Type:
Article
ISSN:
13597345
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorEl Eter, Mohamaden
dc.contributor.authorHamzaoui, Bilelen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorPelletier, Jeremieen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T10:42:36Zen
dc.date.available2015-08-03T10:42:36Zen
dc.date.issued2013en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c3cc40385hen
dc.identifier.urihttp://hdl.handle.net/10754/562557en
dc.description.abstractGrafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.en
dc.publisherRoyal Society of Chemistryen
dc.titleWell-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidationen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalChemical Communicationsen
kaust.authorAbou-Hamad, Edyen
kaust.authorPelletier, Jeremieen
kaust.authorBasset, Jean-Marieen
kaust.authorEl Eter, Mohamaden
kaust.authorHamzaoui, Bilelen
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