Liberation of methyl acrylate from metallalactone complexes via M-O ring opening (M = Ni, Pd) with methylation agents

Handle URI:
http://hdl.handle.net/10754/562536
Title:
Liberation of methyl acrylate from metallalactone complexes via M-O ring opening (M = Ni, Pd) with methylation agents
Authors:
Lee, S. Y Tina; Ghani, Amylia Abdul; D'Elia, Valerio; Cokoja, Mirza; Herrmann, Wolfgang A.; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Kühn, Fritz
Abstract:
Ring opening of various nickela- and palladalactones induced by the cleavage of the M-O bond by methyl trifluoromethanesulfonate (MeOTf) and methyl iodide (MeI) is examined. Experimental evidence supports the mechanism of ring opening by the alkylating agent followed by β-H elimination leading to methyl acrylate and a metal-hydride species. MeOTf shows by far higher efficiency in the lactone ring opening than any other methylating agent including the previously reported methyl iodide. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Royal Society of Chemistry
Journal:
New Journal of Chemistry
Issue Date:
2013
DOI:
10.1039/c3nj00693j
Type:
Article
ISSN:
11440546
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLee, S. Y Tinaen
dc.contributor.authorGhani, Amylia Abdulen
dc.contributor.authorD'Elia, Valerioen
dc.contributor.authorCokoja, Mirzaen
dc.contributor.authorHerrmann, Wolfgang A.en
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorKühn, Fritzen
dc.date.accessioned2015-08-03T10:41:46Zen
dc.date.available2015-08-03T10:41:46Zen
dc.date.issued2013en
dc.identifier.issn11440546en
dc.identifier.doi10.1039/c3nj00693jen
dc.identifier.urihttp://hdl.handle.net/10754/562536en
dc.description.abstractRing opening of various nickela- and palladalactones induced by the cleavage of the M-O bond by methyl trifluoromethanesulfonate (MeOTf) and methyl iodide (MeI) is examined. Experimental evidence supports the mechanism of ring opening by the alkylating agent followed by β-H elimination leading to methyl acrylate and a metal-hydride species. MeOTf shows by far higher efficiency in the lactone ring opening than any other methylating agent including the previously reported methyl iodide. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.en
dc.publisherRoyal Society of Chemistryen
dc.titleLiberation of methyl acrylate from metallalactone complexes via M-O ring opening (M = Ni, Pd) with methylation agentsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalNew Journal of Chemistryen
dc.contributor.institutionDepartment of Inorganic Chemistry/Molecular Catalysis, Catalysis Research Center, Technische Universität München, Ernst-Otto-Fischer-Straße 1, D-85747 Garching bei München, Germanyen
kaust.authorD'Elia, Valerioen
kaust.authorBasset, Jean-Marieen
kaust.authorLee, S. Y Tinaen
kaust.authorGhani, Amylia Abdulen
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