Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

Handle URI:
http://hdl.handle.net/10754/562524
Title:
Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks
Authors:
Elsaidi, Sameh K.; Mohamed, Mona Hassan; Wojtas, Łukasz; Cairns, Amy; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Zaworotko, Michael J.
Abstract:
Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.
KAUST Department:
Chemical Science Program; Physical Sciences and Engineering (PSE) Division; Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Issue Date:
2013
DOI:
10.1039/c3cc44133d
PubMed ID:
23925067
Type:
Article
ISSN:
13597345
Is Supplemented By:
Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943023: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n932; DOI:10.5517/cc10n932; HANDLE:http://hdl.handle.net/10754/624230; Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943025: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n954; DOI:10.5517/cc10n954; HANDLE:http://hdl.handle.net/10754/624232; Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943024: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n943; DOI:10.5517/cc10n943; HANDLE:http://hdl.handle.net/10754/624231
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorElsaidi, Sameh K.en
dc.contributor.authorMohamed, Mona Hassanen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorCairns, Amyen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorZaworotko, Michael J.en
dc.date.accessioned2015-08-03T10:41:20Zen
dc.date.available2015-08-03T10:41:20Zen
dc.date.issued2013en
dc.identifier.issn13597345en
dc.identifier.pmid23925067en
dc.identifier.doi10.1039/c3cc44133den
dc.identifier.urihttp://hdl.handle.net/10754/562524en
dc.description.abstractTwo porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.en
dc.publisherRoyal Society of Chemistryen
dc.titleTwo-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocksen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionDepartment of Chemistry, CHE205, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, United Statesen
dc.contributor.institutionChemistry Department, Faculty of Science, Alexandria University, P.O. Box 426 Ibrahimia, Alexandria 21321, Egypten
kaust.authorCairns, Amyen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByElsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943023: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n932en
dc.relation.isSupplementedByDOI:10.5517/cc10n932en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624230en
dc.relation.isSupplementedByElsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943025: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n954en
dc.relation.isSupplementedByDOI:10.5517/cc10n954en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624232en
dc.relation.isSupplementedByElsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943024: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n943en
dc.relation.isSupplementedByDOI:10.5517/cc10n943en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624231en

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