Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

Handle URI:
http://hdl.handle.net/10754/562522
Title:
Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors
Authors:
Tong, Chenhua; Chang, Jingjing; Tan, Junmin; Dai, Gaole; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Chan, Hardysze; Chi, Chunyan
Abstract:
Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
Royal Society of Chemistry
Journal:
Organic and Biomolecular Chemistry
Issue Date:
2013
DOI:
10.1039/c3ob40982a
PubMed ID:
23884379
Type:
Article
ISSN:
14770520
Sponsors:
This work was financially supported by the Singapore MOE AcRF grants R-143-000-510-112 and NUS Start Up grant R-143-000-486-133 (C. C.) and KAUST (K.-W. H.).
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorTong, Chenhuaen
dc.contributor.authorChang, Jingjingen
dc.contributor.authorTan, Junminen
dc.contributor.authorDai, Gaoleen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorChan, Hardyszeen
dc.contributor.authorChi, Chunyanen
dc.date.accessioned2015-08-03T10:41:16Zen
dc.date.available2015-08-03T10:41:16Zen
dc.date.issued2013en
dc.identifier.issn14770520en
dc.identifier.pmid23884379en
dc.identifier.doi10.1039/c3ob40982aen
dc.identifier.urihttp://hdl.handle.net/10754/562522en
dc.description.abstractSeveral bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.en
dc.description.sponsorshipThis work was financially supported by the Singapore MOE AcRF grants R-143-000-510-112 and NUS Start Up grant R-143-000-486-133 (C. C.) and KAUST (K.-W. H.).en
dc.publisherRoyal Society of Chemistryen
dc.titleBisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistorsen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalOrganic and Biomolecular Chemistryen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singaporeen
kaust.authorHuang, Kuo-Weien

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