A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs

Handle URI:
http://hdl.handle.net/10754/562520
Title:
A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs
Authors:
Zhao, Junpeng; Alamri, Haleema ( 0000-0002-0354-7517 ) ; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
High-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. © 2013 The Royal Society of Chemistry.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Polymer Synthesis Laboratory
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Issue Date:
2013
DOI:
10.1039/c3cc44131h
Type:
Article
ISSN:
13597345
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorZhao, Junpengen
dc.contributor.authorAlamri, Haleemaen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2015-08-03T10:41:11Zen
dc.date.available2015-08-03T10:41:11Zen
dc.date.issued2013en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c3cc44131hen
dc.identifier.urihttp://hdl.handle.net/10754/562520en
dc.description.abstractHigh-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. © 2013 The Royal Society of Chemistry.en
dc.publisherRoyal Society of Chemistryen
dc.titleA facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPolymer Synthesis Laboratoryen
dc.identifier.journalChemical Communicationsen
kaust.authorZhao, Junpengen
kaust.authorHadjichristidis, Nikolaosen
kaust.authorAlamri, Haleemaen
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