Surface grafting of a dense and rigid coordination polymer based on tri-para-carboxy-polychlorotriphenylmethyl radical and copper acetate

Handle URI:
http://hdl.handle.net/10754/562493
Title:
Surface grafting of a dense and rigid coordination polymer based on tri-para-carboxy-polychlorotriphenylmethyl radical and copper acetate
Authors:
Mugnaini, Verónica; Paradinas, Markos; Shekhah, Osama ( 0000-0003-1861-9226 ) ; Roques, Nans; Ocal, Carmen; Wöll, Christof H.; Veciana, Jaume
Abstract:
The step-by-step method is here presented as suitable to anchor on appropriately functionalized gold surfaces a metal-organic coordination polymer based on a non-planar trigonal tri-para-carboxy-polychlorotriphenylmethyl radical derivative and copper acetate. The structural characteristics of the grafted coordination polymer are derived during the step-wise growth from the real time changes in refractive index and oscillation frequency. The film thickness, as measured by scanning force microscopy, combined with the mass uptake value from the quartz crystal microbalance, are used to estimate an average density of the grafted metal-organic coordination polymer that suggests the formation of a dense and rather rigid thin film. This journal is © 2013 The Royal Society of Chemistry.
KAUST Department:
Advanced Membranes and Porous Materials Research Center
Publisher:
Royal Society of Chemistry (RSC)
Journal:
J. Mater. Chem. C
Issue Date:
2013
DOI:
10.1039/c2tc00037g
Type:
Article
ISSN:
20507534
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center

Full metadata record

DC FieldValue Language
dc.contributor.authorMugnaini, Verónicaen
dc.contributor.authorParadinas, Markosen
dc.contributor.authorShekhah, Osamaen
dc.contributor.authorRoques, Nansen
dc.contributor.authorOcal, Carmenen
dc.contributor.authorWöll, Christof H.en
dc.contributor.authorVeciana, Jaumeen
dc.date.accessioned2015-08-03T10:40:07Zen
dc.date.available2015-08-03T10:40:07Zen
dc.date.issued2013en
dc.identifier.issn20507534en
dc.identifier.doi10.1039/c2tc00037gen
dc.identifier.urihttp://hdl.handle.net/10754/562493en
dc.description.abstractThe step-by-step method is here presented as suitable to anchor on appropriately functionalized gold surfaces a metal-organic coordination polymer based on a non-planar trigonal tri-para-carboxy-polychlorotriphenylmethyl radical derivative and copper acetate. The structural characteristics of the grafted coordination polymer are derived during the step-wise growth from the real time changes in refractive index and oscillation frequency. The film thickness, as measured by scanning force microscopy, combined with the mass uptake value from the quartz crystal microbalance, are used to estimate an average density of the grafted metal-organic coordination polymer that suggests the formation of a dense and rather rigid thin film. This journal is © 2013 The Royal Society of Chemistry.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleSurface grafting of a dense and rigid coordination polymer based on tri-para-carboxy-polychlorotriphenylmethyl radical and copper acetateen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.identifier.journalJ. Mater. Chem. Cen
dc.contributor.institutionInstitut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari de la UAB, E-08193 Bellaterra, Spainen
dc.contributor.institutionInstitut für Funktionelle Grenzflächen, Karlsruher Institut für Technologie, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germanyen
kaust.authorShekhah, Osamaen
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