Room-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenes

Handle URI:
http://hdl.handle.net/10754/562437
Title:
Room-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenes
Authors:
Huang, Yuanyuan; Fang, Xin; Lin, Xiaoxi; Li, Huaifeng ( 0000-0001-9661-803X ) ; He, Weiming; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Yuan, Yaofeng; Weng, Zhiqiang
Abstract:
An efficient room temperature copper-catalyzed trifluoromethylation of organotrifluoroborates under the base free condition using an electrophilic trifluoromethylating reagent is demonstrated. The corresponding trifluoromethylarenes were obtained in good to excellent yields and the reaction tolerates a wide range of functional groups. © 2012 Elsevier Ltd. All rights reserved.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
Elsevier BV
Journal:
Tetrahedron
Issue Date:
Dec-2012
DOI:
10.1016/j.tet.2012.09.083
Type:
Article
ISSN:
00404020
Sponsors:
We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W.H.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorHuang, Yuanyuanen
dc.contributor.authorFang, Xinen
dc.contributor.authorLin, Xiaoxien
dc.contributor.authorLi, Huaifengen
dc.contributor.authorHe, Weimingen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorYuan, Yaofengen
dc.contributor.authorWeng, Zhiqiangen
dc.date.accessioned2015-08-03T10:38:11Zen
dc.date.available2015-08-03T10:38:11Zen
dc.date.issued2012-12en
dc.identifier.issn00404020en
dc.identifier.doi10.1016/j.tet.2012.09.083en
dc.identifier.urihttp://hdl.handle.net/10754/562437en
dc.description.abstractAn efficient room temperature copper-catalyzed trifluoromethylation of organotrifluoroborates under the base free condition using an electrophilic trifluoromethylating reagent is demonstrated. The corresponding trifluoromethylarenes were obtained in good to excellent yields and the reaction tolerates a wide range of functional groups. © 2012 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipWe acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W.H.en
dc.publisherElsevier BVen
dc.subjectCopper catalysten
dc.subjectElectrophilic trifluoromethylation reactionen
dc.subjectTrifluoromethylarenesen
dc.titleRoom-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenesen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalTetrahedronen
dc.contributor.institutionDepartment of Chemistry, Fuzhou University, Fuzhou 350108, Chinaen
dc.contributor.institutionFujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, Chinaen
kaust.authorLi, Huaifengen
kaust.authorHuang, Kuo-Weien
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