Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

Handle URI:
http://hdl.handle.net/10754/562435
Title:
Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis
Authors:
Boulanger, Jérôme; Bricout, Hervé; Tilloy, Sébastien; Fihri, Aziz; Len, Christophe; Hapiot, Frédéric; Monflier, Éric
Abstract:
Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.
KAUST Department:
KAUST Catalysis Center (KCC)
Publisher:
Elsevier BV
Journal:
Catalysis Communications
Issue Date:
Dec-2012
DOI:
10.1016/j.catcom.2012.09.019
Type:
Article
ISSN:
15667367
Sponsors:
This work was supported by the Centre National de la Recherche Scientifique (CNRS).
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorBoulanger, Jérômeen
dc.contributor.authorBricout, Hervéen
dc.contributor.authorTilloy, Sébastienen
dc.contributor.authorFihri, Azizen
dc.contributor.authorLen, Christopheen
dc.contributor.authorHapiot, Frédéricen
dc.contributor.authorMonflier, Éricen
dc.date.accessioned2015-08-03T10:38:07Zen
dc.date.available2015-08-03T10:38:07Zen
dc.date.issued2012-12en
dc.identifier.issn15667367en
dc.identifier.doi10.1016/j.catcom.2012.09.019en
dc.identifier.urihttp://hdl.handle.net/10754/562435en
dc.description.abstractTwo new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.en
dc.description.sponsorshipThis work was supported by the Centre National de la Recherche Scientifique (CNRS).en
dc.publisherElsevier BVen
dc.subjectAqueous catalysisen
dc.subjectHydroformylationen
dc.subjectWater soluble phosphaneen
dc.titleWater-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysisen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalCatalysis Communicationsen
dc.contributor.institutionUniversité Lille Nord de France, Unité de Catalyse et de Chimie du Solide, Faculté Jean Perrin, rue Jean Souvraz, SP18, F-62307 Lens Cedex, Franceen
dc.contributor.institutionTransformations Intégrées de la Matière Renouvelable - EA 4297 UTC/ESCOM, Université de Technologie de Compiègne, Centre de Recherches de Royallieu, Rue Personne de Roberval, F-60205 Compiègne Cedex, Franceen
kaust.authorFihri, Azizen
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