[(≢SiO)TaVCl2Me2]: A well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene

Handle URI:
http://hdl.handle.net/10754/562370
Title:
[(≢SiO)TaVCl2Me2]: A well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene
Authors:
Chen, Yin; Callens, Emmanuel; Abou-Hamad, Edy; Merle, Nicolas; White, Andrew J P; Taoufik, Mostafa; Copéret, Christophe; Le Roux, Erwan; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
On the surface of it: In the absence of co-catalyst, a well-defined silica-supported surface organometallic complex [(≢SiO)Ta VCl2Me2] selectively catalyzes the oligomerization of ethylene. The use of surface organometallic species allows three different pathways to be determined for the reduction of TaV to TaIII species under pressure of ethylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Solar and Photovoltaic Engineering Research Center (SPERC)
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
22-Oct-2012
DOI:
10.1002/anie.201206272
Type:
Article
ISSN:
14337851
Sponsors:
We are indebted to Prof. Lyndon Emsley for his enthusiastic discussion and suggestions. The work is supported by KAUST and SABIC.
Is Supplemented By:
Chen, Y., Callens, E., Abou-Hamad, E., Merle, N., White, A. J. P., Taoufik, M., … Basset, J.-M. (2013). CCDC 870534: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccy6vrq; DOI:10.5517/ccy6vrq; HANDLE:http://hdl.handle.net/10754/624686
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Yinen
dc.contributor.authorCallens, Emmanuelen
dc.contributor.authorAbou-Hamad, Edyen
dc.contributor.authorMerle, Nicolasen
dc.contributor.authorWhite, Andrew J Pen
dc.contributor.authorTaoufik, Mostafaen
dc.contributor.authorCopéret, Christopheen
dc.contributor.authorLe Roux, Erwanen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T10:02:48Zen
dc.date.available2015-08-03T10:02:48Zen
dc.date.issued2012-10-22en
dc.identifier.issn14337851en
dc.identifier.doi10.1002/anie.201206272en
dc.identifier.urihttp://hdl.handle.net/10754/562370en
dc.description.abstractOn the surface of it: In the absence of co-catalyst, a well-defined silica-supported surface organometallic complex [(≢SiO)Ta VCl2Me2] selectively catalyzes the oligomerization of ethylene. The use of surface organometallic species allows three different pathways to be determined for the reduction of TaV to TaIII species under pressure of ethylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipWe are indebted to Prof. Lyndon Emsley for his enthusiastic discussion and suggestions. The work is supported by KAUST and SABIC.en
dc.publisherWiley-Blackwellen
dc.subjectethyleneen
dc.subjectoligomerizationen
dc.subjectorganometallic compoundsen
dc.subjectsurface reactionsen
dc.subjecttantalumen
dc.title[(≢SiO)TaVCl2Me2]: A well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethyleneen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.identifier.journalAngewandte Chemie International Editionen
dc.contributor.institutionChimie Organometallique de Surface, Laboratoire de Chimie, ESCPE Lyon, F-308-43 Boulevard du 11 Novembre 1918, F-69616, Villeurbanne Cedex, Franceen
dc.contributor.institutionDepartment of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdomen
dc.contributor.institutionDepartment of Chemistry, University of Bergen, Realfagbygget, Allegaten 41, 5007, Bergen, Norwayen
dc.contributor.institutionDepartment of Chemistry, ETH Zurich, HCI H 229 Wolfgang-Pauli-Strasse 10, 8093, Zurich, Switzerlanden
kaust.authorChen, Yinen
kaust.authorCallens, Emmanuelen
kaust.authorAbou-Hamad, Edyen
kaust.authorBasset, Jean-Marieen
dc.relation.isSupplementedByChen, Y., Callens, E., Abou-Hamad, E., Merle, N., White, A. J. P., Taoufik, M., … Basset, J.-M. (2013). CCDC 870534: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccy6vrqen
dc.relation.isSupplementedByDOI:10.5517/ccy6vrqen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624686en
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