Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors

Handle URI:
http://hdl.handle.net/10754/562362
Title:
Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors
Authors:
Kanimozhi, Catherine K.; Yaacobi-Gross, Nir; Chou, Kang Wei; Amassian, Aram ( 0000-0002-5734-1194 ) ; Anthopoulos, Thomas D.; Patil, Satish P.
Abstract:
In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. © 2012 American Chemical Society.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; Solar and Photovoltaic Engineering Research Center (SPERC); Organic Electronics and Photovoltaics Group
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
10-Oct-2012
DOI:
10.1021/ja308211n
Type:
Article
ISSN:
00027863
Sponsors:
The authors acknowledge financial support from the Department of Science and Technology, India through the Indo-UK Apex Program and Ministry of Communication and Information Technology under a grant for the Centre of Excellence in Nanoelectronics, Phase II. We thank our colleagues Dr. Mallari Naik and Dr. N. Venkatramaiah for the TD-DFT calculations and support. We are grateful to Anke Helfer for GPC measurements. T.D.A. and N.Y.G. are grateful to the Engineering and Physical Sciences Research Council (EPSRC) (Grant EP/J001473/1) and the European Research Council (ERC) for financial support. Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy Office of Science by Stanford University.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorKanimozhi, Catherine K.en
dc.contributor.authorYaacobi-Gross, Niren
dc.contributor.authorChou, Kang Weien
dc.contributor.authorAmassian, Aramen
dc.contributor.authorAnthopoulos, Thomas D.en
dc.contributor.authorPatil, Satish P.en
dc.date.accessioned2015-08-03T10:02:28Zen
dc.date.available2015-08-03T10:02:28Zen
dc.date.issued2012-10-10en
dc.identifier.issn00027863en
dc.identifier.doi10.1021/ja308211nen
dc.identifier.urihttp://hdl.handle.net/10754/562362en
dc.description.abstractIn this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. © 2012 American Chemical Society.en
dc.description.sponsorshipThe authors acknowledge financial support from the Department of Science and Technology, India through the Indo-UK Apex Program and Ministry of Communication and Information Technology under a grant for the Centre of Excellence in Nanoelectronics, Phase II. We thank our colleagues Dr. Mallari Naik and Dr. N. Venkatramaiah for the TD-DFT calculations and support. We are grateful to Anke Helfer for GPC measurements. T.D.A. and N.Y.G. are grateful to the Engineering and Physical Sciences Research Council (EPSRC) (Grant EP/J001473/1) and the European Research Council (ERC) for financial support. Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy Office of Science by Stanford University.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleDiketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistorsen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentMaterials Science and Engineering Programen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.contributor.departmentOrganic Electronics and Photovoltaics Groupen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionSolid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, Indiaen
dc.contributor.institutionDepartment of Physics, Centre for Plastic Electronics, Imperial College London, London SW7 2BW, United Kingdomen
kaust.authorChou, Kang Weien
kaust.authorAmassian, Aramen
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