Synthesis and characterization of new N-(diphenylphosphino)-naphthylamine chalcogenides: X-ray structures of (1-NHC 10H 7)P(Se)Ph 2 and Ph 2P(S)OP(S)Ph 2

Handle URI:
http://hdl.handle.net/10754/562290
Title:
Synthesis and characterization of new N-(diphenylphosphino)-naphthylamine chalcogenides: X-ray structures of (1-NHC 10H 7)P(Se)Ph 2 and Ph 2P(S)OP(S)Ph 2
Authors:
Tomah Al-Masri, Harbi; Emwas, Abdul-Hamid M.; Al-Talla, Zeyad; Al Kordi, Mohamed
Abstract:
The reaction of 1-naphthylamine with one equivalent of chlorodiphenylphosphine in the presence of triethylamine gave the (1-NHC 10H 7)PPh 2 (1) ligand. Refluxing of 1 with elemental sulfur or grey selenium in toluene (1:1 molar ratio) afforded (1-NHC 10H 7)P(S)Ph 2 (2) and (1-NHC 10H 7)P(Se)Ph 2 (3), respectively. Moreover, the byproduct {Ph 2P(S)} 2O (4) was isolated from the reaction of 1 with elemental sulfur. Compounds 1-3 were identified and characterized by multinuclear ( 1H, 13C, 31P, 77Se) NMR spectroscopy, mass spectrometry, and elemental analysis. Crystal structure determinations of 3 and 4 were carried out. Copyright © 2012 Taylor and Francis Group, LLC.
KAUST Department:
Core Labs; Advanced Nanofabrication, Imaging and Characterization Core Lab
Publisher:
Informa UK Limited
Journal:
Phosphorus, Sulfur, and Silicon and the Related Elements
Issue Date:
Sep-2012
DOI:
10.1080/10426507.2012.668985
Type:
Article
ISSN:
10426507
Is Supplemented By:
Al-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844302: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbkkb; DOI:10.5517/ccxbkkb; HANDLE:http://hdl.handle.net/10754/624658; Al-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844303: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbklc; DOI:10.5517/ccxbklc; HANDLE:http://hdl.handle.net/10754/624659
Appears in Collections:
Articles; Advanced Nanofabrication, Imaging and Characterization Core Lab

Full metadata record

DC FieldValue Language
dc.contributor.authorTomah Al-Masri, Harbien
dc.contributor.authorEmwas, Abdul-Hamid M.en
dc.contributor.authorAl-Talla, Zeyaden
dc.contributor.authorAl Kordi, Mohameden
dc.date.accessioned2015-08-03T09:59:33Zen
dc.date.available2015-08-03T09:59:33Zen
dc.date.issued2012-09en
dc.identifier.issn10426507en
dc.identifier.doi10.1080/10426507.2012.668985en
dc.identifier.urihttp://hdl.handle.net/10754/562290en
dc.description.abstractThe reaction of 1-naphthylamine with one equivalent of chlorodiphenylphosphine in the presence of triethylamine gave the (1-NHC 10H 7)PPh 2 (1) ligand. Refluxing of 1 with elemental sulfur or grey selenium in toluene (1:1 molar ratio) afforded (1-NHC 10H 7)P(S)Ph 2 (2) and (1-NHC 10H 7)P(Se)Ph 2 (3), respectively. Moreover, the byproduct {Ph 2P(S)} 2O (4) was isolated from the reaction of 1 with elemental sulfur. Compounds 1-3 were identified and characterized by multinuclear ( 1H, 13C, 31P, 77Se) NMR spectroscopy, mass spectrometry, and elemental analysis. Crystal structure determinations of 3 and 4 were carried out. Copyright © 2012 Taylor and Francis Group, LLC.en
dc.publisherInforma UK Limiteden
dc.subjectAminophosphineen
dc.subjectchalcogenidesen
dc.subjectchlorodiphenylphosphineen
dc.subjectmolecular structureen
dc.subjectphosphineen
dc.titleSynthesis and characterization of new N-(diphenylphosphino)-naphthylamine chalcogenides: X-ray structures of (1-NHC 10H 7)P(Se)Ph 2 and Ph 2P(S)OP(S)Ph 2en
dc.typeArticleen
dc.contributor.departmentCore Labsen
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Laben
dc.identifier.journalPhosphorus, Sulfur, and Silicon and the Related Elementsen
dc.contributor.institutionDepartment of Applied Chemistry, Faculty of Applied Sciences, Taibah University, Madinah 1343, Saudi Arabiaen
kaust.authorEmwas, Abdul-Hamid M.en
kaust.authorAl-Talla, Zeyaden
kaust.authorAl Kordi, Mohameden
dc.relation.isSupplementedByAl-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844302: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbkkben
dc.relation.isSupplementedByDOI:10.5517/ccxbkkben
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624658en
dc.relation.isSupplementedByAl-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844303: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbklcen
dc.relation.isSupplementedByDOI:10.5517/ccxbklcen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624659en
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