Ruthenium(II) pincer complexes with oxazoline arms for efficient transfer hydrogenation reactions

Handle URI:
http://hdl.handle.net/10754/562261
Title:
Ruthenium(II) pincer complexes with oxazoline arms for efficient transfer hydrogenation reactions
Authors:
Chen, Tao; He, Lipeng; Gong, Dirong; Yang, Limin; Miao, Xiaohe; Eppinger, Jorg ( 0000-0001-7886-7059 ) ; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Well-defined P NN CN pincer ruthenium complexes bearing both strong phosphine and weak oxazoline donors were developed. These easily accessible complexes exhibit significantly better catalytic activity in transfer hydrogenation of ketones compared to their PN 3P analogs. These reactions proceed under mild and base-free conditions via protonation- deprotonation of the 'NH' group in the aromatization-dearomatization process. © 2012 Elsevier Ltd. All rights reserved.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Biological & Organometallic Catalysis Laboratories; HCL
Publisher:
Elsevier BV
Journal:
Tetrahedron Letters
Issue Date:
Aug-2012
DOI:
10.1016/j.tetlet.2012.06.041
Type:
Article
ISSN:
00404039
Sponsors:
We are grateful for the generous financial support from the King Abdullah University of Science and Technology.
Is Supplemented By:
Chen, T., He, L.-P., Gong, D., Yang, L., Miao, X., Eppinger, J., & Huang, K.-W. (2012). CCDC 885734: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyqp2d; DOI:10.5517/ccyqp2d; HANDLE:http://hdl.handle.net/10754/624718
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Taoen
dc.contributor.authorHe, Lipengen
dc.contributor.authorGong, Dirongen
dc.contributor.authorYang, Liminen
dc.contributor.authorMiao, Xiaoheen
dc.contributor.authorEppinger, Jorgen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2015-08-03T09:58:27Zen
dc.date.available2015-08-03T09:58:27Zen
dc.date.issued2012-08en
dc.identifier.issn00404039en
dc.identifier.doi10.1016/j.tetlet.2012.06.041en
dc.identifier.urihttp://hdl.handle.net/10754/562261en
dc.description.abstractWell-defined P NN CN pincer ruthenium complexes bearing both strong phosphine and weak oxazoline donors were developed. These easily accessible complexes exhibit significantly better catalytic activity in transfer hydrogenation of ketones compared to their PN 3P analogs. These reactions proceed under mild and base-free conditions via protonation- deprotonation of the 'NH' group in the aromatization-dearomatization process. © 2012 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipWe are grateful for the generous financial support from the King Abdullah University of Science and Technology.en
dc.publisherElsevier BVen
dc.subjectCatalysisen
dc.subjectPinceren
dc.subjectRutheniumen
dc.subjectTransfer hydrogenationen
dc.titleRuthenium(II) pincer complexes with oxazoline arms for efficient transfer hydrogenation reactionsen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentBiological & Organometallic Catalysis Laboratoriesen
dc.contributor.departmentHCLen
dc.identifier.journalTetrahedron Lettersen
kaust.authorHe, Lipengen
kaust.authorGong, Dirongen
kaust.authorMiao, Xiaoheen
kaust.authorEppinger, Jorgen
kaust.authorHuang, Kuo-Weien
kaust.authorChen, Taoen
kaust.authorYang, Liminen
dc.relation.isSupplementedByChen, T., He, L.-P., Gong, D., Yang, L., Miao, X., Eppinger, J., & Huang, K.-W. (2012). CCDC 885734: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyqp2den
dc.relation.isSupplementedByDOI:10.5517/ccyqp2den
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624718en
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