Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes

Handle URI:
http://hdl.handle.net/10754/562258
Title:
Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes
Authors:
Chen, Tao; Yang, Limin; LI, LIANG; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Two types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Advanced Nanofabrication, Imaging and Characterization Core Lab; Core Labs; Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
Elsevier BV
Journal:
Tetrahedron
Issue Date:
Aug-2012
DOI:
10.1016/j.tet.2012.05.075
Type:
Article
ISSN:
00404020
Sponsors:
We are grateful for the generous financial support from King Abdullah University of Science and Technology.
Is Supplemented By:
Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879684: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcxq; DOI:10.5517/ccyjcxq; HANDLE:http://hdl.handle.net/10754/624711; Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879685: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcyr; DOI:10.5517/ccyjcyr; HANDLE:http://hdl.handle.net/10754/624712; Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879686: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjczs; DOI:10.5517/ccyjczs; HANDLE:http://hdl.handle.net/10754/624713
Appears in Collections:
Articles; Advanced Nanofabrication, Imaging and Characterization Core Lab; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorChen, Taoen
dc.contributor.authorYang, Liminen
dc.contributor.authorLI, LIANGen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2015-08-03T09:58:20Zen
dc.date.available2015-08-03T09:58:20Zen
dc.date.issued2012-08en
dc.identifier.issn00404020en
dc.identifier.doi10.1016/j.tet.2012.05.075en
dc.identifier.urihttp://hdl.handle.net/10754/562258en
dc.description.abstractTwo types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipWe are grateful for the generous financial support from King Abdullah University of Science and Technology.en
dc.publisherElsevier BVen
dc.subjectCatalysisen
dc.subjectHomocouplingen
dc.subjectNickelen
dc.subjectPinceren
dc.titleHomocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexesen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Laben
dc.contributor.departmentCore Labsen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalTetrahedronen
kaust.authorLI, LIANGen
kaust.authorHuang, Kuo-Weien
kaust.authorChen, Taoen
kaust.authorYang, Liminen
dc.relation.isSupplementedByChen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879684: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcxqen
dc.relation.isSupplementedByDOI:10.5517/ccyjcxqen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624711en
dc.relation.isSupplementedByChen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879685: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcyren
dc.relation.isSupplementedByDOI:10.5517/ccyjcyren
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624712en
dc.relation.isSupplementedByChen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879686: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjczsen
dc.relation.isSupplementedByDOI:10.5517/ccyjczsen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624713en
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