Enhanced reactivities toward amines by introducing an imine arm to the pincer ligand: Direct coupling of two amines to form an imine without oxidant

Handle URI:
http://hdl.handle.net/10754/562245
Title:
Enhanced reactivities toward amines by introducing an imine arm to the pincer ligand: Direct coupling of two amines to form an imine without oxidant
Authors:
He, Lipeng; Chen, Tao; Gong, Dirong; Lai, Zhiping ( 0000-0001-9555-6009 ) ; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Dehydrogenative homocoupling of primary alcohols to form esters and coupling of amines to form imines was accomplished using a class of novel pincer ruthenium complexes. The reactivities of the ruthenium pincer complexes for the direct coupling of amines to form imines were enhanced by introducing an imine arm to the pincer ligand. Selective oxidation of benzylamines to imines was achieved using aniline derivatives as the substrate and solvent. © 2012 American Chemical Society.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Numerical Porous Media SRI Center (NumPor); Physical Sciences and Engineering (PSE) Division; Chemical and Biological Engineering Program; Advanced Membranes and Porous Materials Research Center; Chemical Science Program; HCL
Publisher:
American Chemical Society (ACS)
Journal:
Organometallics
Issue Date:
23-Jul-2012
DOI:
10.1021/om300422v
Type:
Article
ISSN:
02767333
Sponsors:
We are grateful for generous financial support from King Abdullah University of Science and Technology. We thank Prof. Hsiao-hua Yu (RIKEN) for useful discussions.
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Chemical and Biological Engineering Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorHe, Lipengen
dc.contributor.authorChen, Taoen
dc.contributor.authorGong, Dirongen
dc.contributor.authorLai, Zhipingen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2015-08-03T09:57:49Zen
dc.date.available2015-08-03T09:57:49Zen
dc.date.issued2012-07-23en
dc.identifier.issn02767333en
dc.identifier.doi10.1021/om300422ven
dc.identifier.urihttp://hdl.handle.net/10754/562245en
dc.description.abstractDehydrogenative homocoupling of primary alcohols to form esters and coupling of amines to form imines was accomplished using a class of novel pincer ruthenium complexes. The reactivities of the ruthenium pincer complexes for the direct coupling of amines to form imines were enhanced by introducing an imine arm to the pincer ligand. Selective oxidation of benzylamines to imines was achieved using aniline derivatives as the substrate and solvent. © 2012 American Chemical Society.en
dc.description.sponsorshipWe are grateful for generous financial support from King Abdullah University of Science and Technology. We thank Prof. Hsiao-hua Yu (RIKEN) for useful discussions.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleEnhanced reactivities toward amines by introducing an imine arm to the pincer ligand: Direct coupling of two amines to form an imine without oxidanten
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentNumerical Porous Media SRI Center (NumPor)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical and Biological Engineering Programen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentHCLen
dc.identifier.journalOrganometallicsen
kaust.authorHe, Lipengen
kaust.authorGong, Dirongen
kaust.authorLai, Zhipingen
kaust.authorHuang, Kuo-Weien
kaust.authorChen, Taoen
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