Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Handle URI:
http://hdl.handle.net/10754/562061
Title:
Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins
Authors:
Zhang, ZhenJie; Zhang, Linping; Wojtas, Łukasz; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Zaworotko, Michael J.
Abstract:
meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.
KAUST Department:
Chemical Science Program; Physical Sciences and Engineering (PSE) Division; Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society
Journal:
Journal of the American Chemical Society
Issue Date:
18-Jan-2012
DOI:
10.1021/ja208256u
Type:
Article
ISSN:
00027863
Sponsors:
This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorZhang, ZhenJieen
dc.contributor.authorZhang, Linpingen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorZaworotko, Michael J.en
dc.date.accessioned2015-08-03T09:43:50Zen
dc.date.available2015-08-03T09:43:50Zen
dc.date.issued2012-01-18en
dc.identifier.issn00027863en
dc.identifier.doi10.1021/ja208256uen
dc.identifier.urihttp://hdl.handle.net/10754/562061en
dc.description.abstractmeso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.en
dc.description.sponsorshipThis publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.en
dc.publisherAmerican Chemical Societyen
dc.titleTemplate-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrinsen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United Statesen
kaust.authorEddaoudi, Mohameden
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