Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Handle URI:
http://hdl.handle.net/10754/562060
Title:
Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material
Authors:
Zhang, ZhenJie; Zhang, Linping; Wojtas, Łukasz; Nugent, Patrick S.; Eddaoudi, Mohamed ( 0000-0003-1916-9837 ) ; Zaworotko, Michael J.
Abstract:
Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.
KAUST Department:
Chemical Science Program; Physical Sciences and Engineering (PSE) Division; Advanced Membranes and Porous Materials Research Center; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society
Journal:
Journal of the American Chemical Society
Issue Date:
18-Jan-2012
DOI:
10.1021/ja209643b
Type:
Article
ISSN:
00027863
Sponsors:
This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorZhang, ZhenJieen
dc.contributor.authorZhang, Linpingen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorNugent, Patrick S.en
dc.contributor.authorEddaoudi, Mohameden
dc.contributor.authorZaworotko, Michael J.en
dc.date.accessioned2015-08-03T09:43:49Zen
dc.date.available2015-08-03T09:43:49Zen
dc.date.issued2012-01-18en
dc.identifier.issn00027863en
dc.identifier.doi10.1021/ja209643ben
dc.identifier.urihttp://hdl.handle.net/10754/562060en
dc.description.abstractReaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.en
dc.description.sponsorshipThis publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).en
dc.publisherAmerican Chemical Societyen
dc.titleTemplated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic materialen
dc.typeArticleen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United Statesen
kaust.authorEddaoudi, Mohameden
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