Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts

Handle URI:
http://hdl.handle.net/10754/562026
Title:
Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts
Authors:
Garron, Anthony; Stoffelbach, François; Merle, Nicolas; Szeto, Kaï Chung; Thivolle-Cazat, Jean; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Norsic, Sébastien; Taoufik, Mostafa
Abstract:
2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Royal Society of Chemistry
Journal:
Catalysis Science and Technology
Issue Date:
2012
DOI:
10.1039/c2cy20539d
Type:
Article
ISSN:
20444753
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorGarron, Anthonyen
dc.contributor.authorStoffelbach, Françoisen
dc.contributor.authorMerle, Nicolasen
dc.contributor.authorSzeto, Kaï Chungen
dc.contributor.authorThivolle-Cazat, Jeanen
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorNorsic, Sébastienen
dc.contributor.authorTaoufik, Mostafaen
dc.date.accessioned2015-08-03T09:43:06Zen
dc.date.available2015-08-03T09:43:06Zen
dc.date.issued2012en
dc.identifier.issn20444753en
dc.identifier.doi10.1039/c2cy20539den
dc.identifier.urihttp://hdl.handle.net/10754/562026en
dc.description.abstract2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.en
dc.publisherRoyal Society of Chemistryen
dc.titleImproved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalystsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalCatalysis Science and Technologyen
dc.contributor.institutionUniversité Lyon 1, Institut de Chimie de Lyon, LCOMS Bâtiment 308, F 43 Blvd du 11 Novembre 1918, F-69616, Villeurbanne Cedex, Franceen
dc.contributor.institutionUPMC, Université Paris 6, UMR 7610, 3, rue Galilée, 94200 Ivry sur Seine, Franceen
kaust.authorBasset, Jean-Marieen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.