Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts

Handle URI:
http://hdl.handle.net/10754/562026
Title:
Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts
Authors:
Garron, Anthony; Stoffelbach, François; Merle, Nicolas; Szeto, Kaï Chung; Thivolle-Cazat, Jean; Basset, Jean-Marie ( 0000-0003-3166-8882 ) ; Norsic, Sébastien; Taoufik, Mostafa
Abstract:
2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Catalysis Science & Technology
Issue Date:
2012
DOI:
10.1039/c2cy20539d
Type:
Article
ISSN:
20444753
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorGarron, Anthonyen
dc.contributor.authorStoffelbach, Françoisen
dc.contributor.authorMerle, Nicolasen
dc.contributor.authorSzeto, Kaï Chungen
dc.contributor.authorThivolle-Cazat, Jeanen
dc.contributor.authorBasset, Jean-Marieen
dc.contributor.authorNorsic, Sébastienen
dc.contributor.authorTaoufik, Mostafaen
dc.date.accessioned2015-08-03T09:43:06Zen
dc.date.available2015-08-03T09:43:06Zen
dc.date.issued2012en
dc.identifier.issn20444753en
dc.identifier.doi10.1039/c2cy20539den
dc.identifier.urihttp://hdl.handle.net/10754/562026en
dc.description.abstract2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleImproved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalystsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalCatalysis Science & Technologyen
dc.contributor.institutionUniversité Lyon 1, Institut de Chimie de Lyon, LCOMS Bâtiment 308, F 43 Blvd du 11 Novembre 1918, F-69616, Villeurbanne Cedex, Franceen
dc.contributor.institutionUPMC, Université Paris 6, UMR 7610, 3, rue Galilée, 94200 Ivry sur Seine, Franceen
kaust.authorBasset, Jean-Marieen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.