Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Handle URI:
http://hdl.handle.net/10754/562008
Title:
Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins
Authors:
Zeng, Wangdong; Lee, Byungsun; Sung, Youngmo; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Li, Yuan; Kim, Dongho; Wu, Jishan
Abstract:
4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Issue Date:
2012
DOI:
10.1039/c2cc33728b
Type:
Article
ISSN:
13597345
Sponsors:
J. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorZeng, Wangdongen
dc.contributor.authorLee, Byungsunen
dc.contributor.authorSung, Youngmoen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorLi, Yuanen
dc.contributor.authorKim, Donghoen
dc.contributor.authorWu, Jishanen
dc.date.accessioned2015-08-03T09:36:08Zen
dc.date.available2015-08-03T09:36:08Zen
dc.date.issued2012en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c2cc33728ben
dc.identifier.urihttp://hdl.handle.net/10754/562008en
dc.description.abstract4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.en
dc.description.sponsorshipJ. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.en
dc.publisherRoyal Society of Chemistryen
dc.titleTetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrinsen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore, Singaporeen
dc.contributor.institutionSpectroscopy Laboratory for Functional pi-Electronic Systems, Department of Chemistry, Yonsei University, Seoul 120-749, South Koreaen
dc.contributor.institutionInstitute of Materials Research and Engineering, A Star 3 Research Link, C 117602 Singapore, Singaporeen
kaust.authorHuang, Kuo-Weien
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