Asymmetric H-D exchange reactions of fluorinated aromatic ketones

Handle URI:
http://hdl.handle.net/10754/561983
Title:
Asymmetric H-D exchange reactions of fluorinated aromatic ketones
Authors:
Zhao, Yujun; Lim, XiaoZhi; Pan, Yuanhang; Zong, Lili; Feng, Wei; Tan, Choonhong; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity. © 2012 The Royal Society of Chemistry.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chemical Communications
Issue Date:
2012
DOI:
10.1039/c2cc31443f
Type:
Article
ISSN:
13597345
Sponsors:
We wish to thank the National University of Singapore and King Abdullah University of Science and Technology for their generous financial support.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorZhao, Yujunen
dc.contributor.authorLim, XiaoZhien
dc.contributor.authorPan, Yuanhangen
dc.contributor.authorZong, Lilien
dc.contributor.authorFeng, Weien
dc.contributor.authorTan, Choonhongen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2015-08-03T09:35:35Zen
dc.date.available2015-08-03T09:35:35Zen
dc.date.issued2012en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/c2cc31443fen
dc.identifier.urihttp://hdl.handle.net/10754/561983en
dc.description.abstractChiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity. © 2012 The Royal Society of Chemistry.en
dc.description.sponsorshipWe wish to thank the National University of Singapore and King Abdullah University of Science and Technology for their generous financial support.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.titleAsymmetric H-D exchange reactions of fluorinated aromatic ketonesen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore 3, Science Drive 3, 117543 Singapore, Singaporeen
kaust.authorLim, XiaoZhien
kaust.authorHuang, Kuo-Weien
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