The next chapter in MOF pillaring strategies: Trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms

Handle URI:
http://hdl.handle.net/10754/561917
Title:
The next chapter in MOF pillaring strategies: Trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms
Authors:
Eubank, Jarrod F.; Wojtas, Łukasz; Hight, Matthew R.; Bousquet, Till; Kravtsov, Victor Ch H; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
A new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated. Trigonal heterofunctional ligands, in this case isophthalic acid cores functionalized at the 5-position with N-donor (e.g., pyridyl- or triazolyl-type) moieties, are designed and utilized to pillar pretargeted two-dimensional layers (supermolecular building layers, SBLs). These SBLs, based on edge transitive Kagomé and square lattices, are cross-linked into predicted three-dimensional MOFs with tunable large cavities, resulting in isoreticular platforms. © 2011 American Chemical Society.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
9-Nov-2011
DOI:
10.1021/ja203898s
PubMed ID:
21675767
Type:
Article
ISSN:
00027863
Sponsors:
We gratefully acknowledge NSF (DMR 0548117) and KAUST Funds. Renee D. Shellhammer is thanked for cover art design.
Is Supplemented By:
Eubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408287: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fmv; DOI:10.5517/cc1j8fmv; HANDLE:http://hdl.handle.net/10754/624439; Eubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408288: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fnw; DOI:10.5517/cc1j8fnw; HANDLE:http://hdl.handle.net/10754/624440; Eubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408289: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fpx; DOI:10.5517/cc1j8fpx; HANDLE:http://hdl.handle.net/10754/624441; Eubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408290: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fqy; DOI:10.5517/cc1j8fqy; HANDLE:http://hdl.handle.net/10754/624442; Eubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408291: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8frz; DOI:10.5517/cc1j8frz; HANDLE:http://hdl.handle.net/10754/624443
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorEubank, Jarrod F.en
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorHight, Matthew R.en
dc.contributor.authorBousquet, Tillen
dc.contributor.authorKravtsov, Victor Ch Hen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2015-08-03T09:34:04Zen
dc.date.available2015-08-03T09:34:04Zen
dc.date.issued2011-11-09en
dc.identifier.issn00027863en
dc.identifier.pmid21675767en
dc.identifier.doi10.1021/ja203898sen
dc.identifier.urihttp://hdl.handle.net/10754/561917en
dc.description.abstractA new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated. Trigonal heterofunctional ligands, in this case isophthalic acid cores functionalized at the 5-position with N-donor (e.g., pyridyl- or triazolyl-type) moieties, are designed and utilized to pillar pretargeted two-dimensional layers (supermolecular building layers, SBLs). These SBLs, based on edge transitive Kagomé and square lattices, are cross-linked into predicted three-dimensional MOFs with tunable large cavities, resulting in isoreticular platforms. © 2011 American Chemical Society.en
dc.description.sponsorshipWe gratefully acknowledge NSF (DMR 0548117) and KAUST Funds. Renee D. Shellhammer is thanked for cover art design.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleThe next chapter in MOF pillaring strategies: Trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platformsen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620, United Statesen
dc.contributor.institutionInstitute of Applied Physics, Academy of Sciences of Moldova, Academy str. 5, MD2028 Chisinau, Moldovaen
kaust.authorEddaoudi, Mohameden
dc.relation.isSupplementedByEubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408287: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fmven
dc.relation.isSupplementedByDOI:10.5517/cc1j8fmven
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624439en
dc.relation.isSupplementedByEubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408288: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fnwen
dc.relation.isSupplementedByDOI:10.5517/cc1j8fnwen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624440en
dc.relation.isSupplementedByEubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408289: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fpxen
dc.relation.isSupplementedByDOI:10.5517/cc1j8fpxen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624441en
dc.relation.isSupplementedByEubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408290: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8fqyen
dc.relation.isSupplementedByDOI:10.5517/cc1j8fqyen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624442en
dc.relation.isSupplementedByEubank, J. F., Wojtas, L., Hight, M. R., Bousquet, T., Kravtsov, V. C., & Eddaoudi, M. (2015). CCDC 1408291: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1j8frzen
dc.relation.isSupplementedByDOI:10.5517/cc1j8frzen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624443en

Related articles on PubMed

All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.