Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)

Handle URI:
http://hdl.handle.net/10754/561906
Title:
Synthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)
Authors:
Mehenni, Hakim; Bakr, Osman M. ( 0000-0002-3428-1002 )
Abstract:
Novel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. © 2011 Elsevier Ltd. All rights reserved.
KAUST Department:
Functional Nanomaterials Lab (FuNL); Materials Science and Engineering Program; Physical Sciences and Engineering (PSE) Division; Solar and Photovoltaic Engineering Research Center (SPERC); KAUST Catalysis Center (KCC)
Publisher:
Elsevier
Journal:
Reactive and Functional Polymers
Issue Date:
Nov-2011
DOI:
10.1016/j.reactfunctpolym.2011.07.011
Type:
Article
ISSN:
13815148
Sponsors:
This work was supported by a grant from the Wallonia region (Belgium) and King Abdullah University of Science and Technology (Saudi Arabia).
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Materials Science and Engineering Program; KAUST Catalysis Center (KCC); Solar and Photovoltaic Engineering Research Center (SPERC)

Full metadata record

DC FieldValue Language
dc.contributor.authorMehenni, Hakimen
dc.contributor.authorBakr, Osman M.en
dc.date.accessioned2015-08-03T09:33:48Zen
dc.date.available2015-08-03T09:33:48Zen
dc.date.issued2011-11en
dc.identifier.issn13815148en
dc.identifier.doi10.1016/j.reactfunctpolym.2011.07.011en
dc.identifier.urihttp://hdl.handle.net/10754/561906en
dc.description.abstractNovel bis(perfluorophenyl azides) coupling agents, containing spacer arms from ethylene or ethylene glycol subunits, were successfully synthesized. Nitrenes photogenerated from these novel bis(PFPA) coupling agents were applied successfully to the cross-linking of poly(ethylene oxide) (PEO10,000) in either aqueous medium or at the solid state, thus, we demonstrated the potential of these bis(PFPA) molecules as promising coupling agents in surface engineering. © 2011 Elsevier Ltd. All rights reserved.en
dc.description.sponsorshipThis work was supported by a grant from the Wallonia region (Belgium) and King Abdullah University of Science and Technology (Saudi Arabia).en
dc.publisherElsevieren
dc.subjectBis(perfluorophenyl azides)en
dc.subjectCoupling agentsen
dc.subjectCovalent networksen
dc.subjectCrosslinkingen
dc.subjectNitreneen
dc.subjectPhotoactivationen
dc.subjectPoly(ethylene oxide)en
dc.subjectSpacer armen
dc.titleSynthesis of novel bis(perfluorophenyl azides) coupling agents: Evaluation of their performance by crosslinking of poly(ethylene oxide)en
dc.typeArticleen
dc.contributor.departmentFunctional Nanomaterials Lab (FuNL)en
dc.contributor.departmentMaterials Science and Engineering Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentSolar and Photovoltaic Engineering Research Center (SPERC)en
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalReactive and Functional Polymersen
dc.contributor.institutionUnité de Chimie Organique et Médicinale, Université Catholique de Louvain, B-1348 Louvain-la-Neuve, Belgiumen
kaust.authorMehenni, Hakimen
kaust.authorBakr, Osman M.en
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