The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks

Handle URI:
http://hdl.handle.net/10754/561875
Title:
The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks
Authors:
Eubank, Jarrod F.; Mouttaki, Hasnaa; Cairns, Amy; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Wojtas, Łukasz; Luebke, Ryan ( 0000-0002-1285-3321 ) ; Al Kordi, Mohamed; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.
KAUST Department:
Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Functional Materials Design, Discovery and Development (FMD3)
Publisher:
American Chemical Society (ACS)
Journal:
Journal of the American Chemical Society
Issue Date:
14-Sep-2011
DOI:
10.1021/ja205658j
Type:
Article
ISSN:
00027863
Sponsors:
This work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).
Is Supplemented By:
Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855129: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptt6; DOI:10.5517/ccxptt6; HANDLE:http://hdl.handle.net/10754/624665; Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855128: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxpts5; DOI:10.5517/ccxpts5; HANDLE:http://hdl.handle.net/10754/624664; Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855130: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptv7; DOI:10.5517/ccxptv7; HANDLE:http://hdl.handle.net/10754/624666
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorEubank, Jarrod F.en
dc.contributor.authorMouttaki, Hasnaaen
dc.contributor.authorCairns, Amyen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorWojtas, Łukaszen
dc.contributor.authorLuebke, Ryanen
dc.contributor.authorAl Kordi, Mohameden
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2015-08-03T09:33:02Zen
dc.date.available2015-08-03T09:33:02Zen
dc.date.issued2011-09-14en
dc.identifier.issn00027863en
dc.identifier.doi10.1021/ja205658jen
dc.identifier.urihttp://hdl.handle.net/10754/561875en
dc.description.abstractA new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.en
dc.description.sponsorshipThis work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleThe quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocksen
dc.typeArticleen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620, United Statesen
kaust.authorCairns, Amyen
kaust.authorBelmabkhout, Youssefen
kaust.authorLuebke, Ryanen
kaust.authorEddaoudi, Mohameden
kaust.authorAl Kordi, Mohameden
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855129: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptt6en
dc.relation.isSupplementedByDOI:10.5517/ccxptt6en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624665en
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855128: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxpts5en
dc.relation.isSupplementedByDOI:10.5517/ccxpts5en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624664en
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855130: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptv7en
dc.relation.isSupplementedByDOI:10.5517/ccxptv7en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624666en
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