Soluble and stable heptazethrenebis(dicarboximide) with a singlet open-shell ground state

Handle URI:
http://hdl.handle.net/10754/561840
Title:
Soluble and stable heptazethrenebis(dicarboximide) with a singlet open-shell ground state
Authors:
Sun, Zhe; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Wu, Jishan
Abstract:
A soluble and stable heptazethrene derivative was synthesized and characterized for the first time. This molecule exhibits a singlet biradical character in the ground state, which is the first case among zethrene homologue series. Exceptional stability of this heptazethrenebis(dicarboximide) raises the likelihood of its practical applications in materials science. © 2011 American Chemical Society.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
American Chemical Society
Journal:
Journal of the American Chemical Society
Issue Date:
10-Aug-2011
DOI:
10.1021/ja204501m
PubMed ID:
21755946
Type:
Article
ISSN:
00027863
Sponsors:
J.W. acknowledges the financial support from NUS Young Investigator Award (R-143-000-356-101), NRF Competitive Research Program (R-143-000-360-281), and A*Star BMRC-NMRC Joint Grant (10/1/21/19/642). K-W.H. acknowledges the financial support from KAUST. We thank Professor Richard D. Webster for the ESR measurement and Professor Yuan-Chung Cheng, Dr. Bei Zhang Professor Xixiang Zhang, and Dr. D. J. Fox for useful discussions.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorSun, Zheen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorWu, Jishanen
dc.date.accessioned2015-08-03T09:32:10Zen
dc.date.available2015-08-03T09:32:10Zen
dc.date.issued2011-08-10en
dc.identifier.issn00027863en
dc.identifier.pmid21755946en
dc.identifier.doi10.1021/ja204501men
dc.identifier.urihttp://hdl.handle.net/10754/561840en
dc.description.abstractA soluble and stable heptazethrene derivative was synthesized and characterized for the first time. This molecule exhibits a singlet biradical character in the ground state, which is the first case among zethrene homologue series. Exceptional stability of this heptazethrenebis(dicarboximide) raises the likelihood of its practical applications in materials science. © 2011 American Chemical Society.en
dc.description.sponsorshipJ.W. acknowledges the financial support from NUS Young Investigator Award (R-143-000-356-101), NRF Competitive Research Program (R-143-000-360-281), and A*Star BMRC-NMRC Joint Grant (10/1/21/19/642). K-W.H. acknowledges the financial support from KAUST. We thank Professor Richard D. Webster for the ESR measurement and Professor Yuan-Chung Cheng, Dr. Bei Zhang Professor Xixiang Zhang, and Dr. D. J. Fox for useful discussions.en
dc.publisherAmerican Chemical Societyen
dc.titleSoluble and stable heptazethrenebis(dicarboximide) with a singlet open-shell ground stateen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalJournal of the American Chemical Societyen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore, Singaporeen
kaust.authorHuang, Kuo-Weien

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