"Hydro-metathesis" of olefins: A catalytic reaction using a bifunctional single-site tantalum hydride catalyst supported on fibrous silica (KCC-1) nanospheres

Handle URI:
http://hdl.handle.net/10754/561715
Title:
"Hydro-metathesis" of olefins: A catalytic reaction using a bifunctional single-site tantalum hydride catalyst supported on fibrous silica (KCC-1) nanospheres
Authors:
Polshettiwar, Vivek ( 0000-0003-1375-9668 ) ; Thivolle-Cazat, Jean; Taoufik, Mostafa; Stoffelbach, François; Norsic, Sébastien; Basset, Jean-Marie ( 0000-0003-3166-8882 )
Abstract:
Tantalizing hydrocarbons: Tantalum hydride supported on fibrous silica nanospheres (KCC-1) catalyzes, in the presence of hydrogen, the direct conversion of olefins into alkanes that have higher and lower numbers of carbon atoms (see scheme). This catalyst shows remarkable catalytic activity and stability, with excellent potential of regeneration. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division; Chemical Science Program
Publisher:
Wiley-Blackwell
Journal:
Angewandte Chemie International Edition
Issue Date:
18-Feb-2011
DOI:
10.1002/anie.201007254
Type:
Article
ISSN:
14337851
Sponsors:
We thank ESCPE-Lyon, the CNRS, and the KAUST for financial and logistic support and Anne Baudouin for NMR spectra acquisition.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorPolshettiwar, Viveken
dc.contributor.authorThivolle-Cazat, Jeanen
dc.contributor.authorTaoufik, Mostafaen
dc.contributor.authorStoffelbach, Françoisen
dc.contributor.authorNorsic, Sébastienen
dc.contributor.authorBasset, Jean-Marieen
dc.date.accessioned2015-08-03T09:02:58Zen
dc.date.available2015-08-03T09:02:58Zen
dc.date.issued2011-02-18en
dc.identifier.issn14337851en
dc.identifier.doi10.1002/anie.201007254en
dc.identifier.urihttp://hdl.handle.net/10754/561715en
dc.description.abstractTantalizing hydrocarbons: Tantalum hydride supported on fibrous silica nanospheres (KCC-1) catalyzes, in the presence of hydrogen, the direct conversion of olefins into alkanes that have higher and lower numbers of carbon atoms (see scheme). This catalyst shows remarkable catalytic activity and stability, with excellent potential of regeneration. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipWe thank ESCPE-Lyon, the CNRS, and the KAUST for financial and logistic support and Anne Baudouin for NMR spectra acquisition.en
dc.publisherWiley-Blackwellen
dc.subjectalkanesen
dc.subjectalkenesen
dc.subjectmetathesisen
dc.subjectnanoparticlesen
dc.subjectsupported catalystsen
dc.title"Hydro-metathesis" of olefins: A catalytic reaction using a bifunctional single-site tantalum hydride catalyst supported on fibrous silica (KCC-1) nanospheresen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.identifier.journalAngewandte Chemie International Editionen
dc.contributor.institutionUniversité de Lyon 1, Institut de Chimie de Lyon, UMR 5265 C2P2, 43 Blvd du 11 Novembre 1918, F-69616, Villeurbanne Cedex, Franceen
kaust.authorPolshettiwar, Viveken
kaust.authorBasset, Jean-Marieen
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