H-shaped oligothiophenes with low band gaps and amphoteric redox properties

Handle URI:
http://hdl.handle.net/10754/561585
Title:
H-shaped oligothiophenes with low band gaps and amphoteric redox properties
Authors:
Luo, Jing; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Qu, Hemi; Zhang, Xiaojie; Zhu, Lijun; Chan, Hardysze; Chi, Chunyan
Abstract:
H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
17-Dec-2010
DOI:
10.1021/ol102456c
Type:
Article
ISSN:
15237060
Sponsors:
We acknowledge financial support from AcRF Tier 1 FRC grants R-143-000-444-112, R-143-000-412-112, and R-143-000-370-112 to C.C. and from KAUST baseline funding to K.-W.H.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorLuo, Jingen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorQu, Hemien
dc.contributor.authorZhang, Xiaojieen
dc.contributor.authorZhu, Lijunen
dc.contributor.authorChan, Hardyszeen
dc.contributor.authorChi, Chunyanen
dc.date.accessioned2015-08-02T09:14:46Zen
dc.date.available2015-08-02T09:14:46Zen
dc.date.issued2010-12-17en
dc.identifier.issn15237060en
dc.identifier.doi10.1021/ol102456cen
dc.identifier.urihttp://hdl.handle.net/10754/561585en
dc.description.abstractH-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.en
dc.description.sponsorshipWe acknowledge financial support from AcRF Tier 1 FRC grants R-143-000-444-112, R-143-000-412-112, and R-143-000-370-112 to C.C. and from KAUST baseline funding to K.-W.H.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleH-shaped oligothiophenes with low band gaps and amphoteric redox propertiesen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalOrganic Lettersen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singaporeen
dc.contributor.institutionSchool of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Chinaen
kaust.authorHuang, Kuo-Weien
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