Soluble and stable zethrenebis(dicarboximide) and its quinone

Handle URI:
http://hdl.handle.net/10754/561541
Title:
Soluble and stable zethrenebis(dicarboximide) and its quinone
Authors:
Sun, Zhe; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Wu, Jishan
Abstract:
Soluble and stable zethrenebis(dicarboximide) (1) was synthesized by an in situ Stille cross coupling/transannular cyclization reaction. 1 showed largely improved photostability and solubility compared with the very unstable zethrene and it also exhibited far-red absorption and emission with high photoluminescence quantum yield. Bromination of 1 with NBS/DMF gave its quinone form 2 via an unusual pathway. © 2010 American Chemical Society.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
15-Oct-2010
DOI:
10.1021/ol102088j
Type:
Article
ISSN:
15237060
Sponsors:
J W would like to acknowledge financial support from Singapore DSTA DIRP Project (DSTA-NUS-DIRP/2008/03), the NRF Competitive Research Program (R-143-000-360-281), and NUS Young Investigator Award (R-143-000-356-101) K-W H acknowledges the financial support from KAUST
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorSun, Zheen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorWu, Jishanen
dc.date.accessioned2015-08-02T09:13:48Zen
dc.date.available2015-08-02T09:13:48Zen
dc.date.issued2010-10-15en
dc.identifier.issn15237060en
dc.identifier.doi10.1021/ol102088jen
dc.identifier.urihttp://hdl.handle.net/10754/561541en
dc.description.abstractSoluble and stable zethrenebis(dicarboximide) (1) was synthesized by an in situ Stille cross coupling/transannular cyclization reaction. 1 showed largely improved photostability and solubility compared with the very unstable zethrene and it also exhibited far-red absorption and emission with high photoluminescence quantum yield. Bromination of 1 with NBS/DMF gave its quinone form 2 via an unusual pathway. © 2010 American Chemical Society.en
dc.description.sponsorshipJ W would like to acknowledge financial support from Singapore DSTA DIRP Project (DSTA-NUS-DIRP/2008/03), the NRF Competitive Research Program (R-143-000-360-281), and NUS Young Investigator Award (R-143-000-356-101) K-W H acknowledges the financial support from KAUSTen
dc.publisherAmerican Chemical Society (ACS)en
dc.titleSoluble and stable zethrenebis(dicarboximide) and its quinoneen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalOrganic Lettersen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singaporeen
kaust.authorHuang, Kuo-Weien
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