N-annulated perylene fused porphyrins with enhanced near-IR absorption and emission

Handle URI:
http://hdl.handle.net/10754/561523
Title:
N-annulated perylene fused porphyrins with enhanced near-IR absorption and emission
Authors:
Jiao, Chongjun; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Guan, Zhenping; Xu, Qinghua; Wu, Jishan
Abstract:
N-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)3/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-β doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes. © 2010 American Chemical Society.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division; KAUST Catalysis Center (KCC); Chemical Science Program; Physical Sciences and Engineering (PSE) Division; HCL
Publisher:
American Chemical Society (ACS)
Journal:
Organic Letters
Issue Date:
17-Sep-2010
DOI:
10.1021/ol1016383
PubMed ID:
20734983
Type:
Article
ISSN:
15237060
Sponsors:
This work was financially supported by Singapore DSTA DIRP Project (DSTA-NUS-DIRP/2008/03), the NRF Competitive Research Program (R-143-000-360-281), and NUS Young Investigator Award (R-143-000-356-101) to J.W. and a KAUST baseline funding to K.-W.H.
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorJiao, Chongjunen
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorGuan, Zhenpingen
dc.contributor.authorXu, Qinghuaen
dc.contributor.authorWu, Jishanen
dc.date.accessioned2015-08-02T09:13:25Zen
dc.date.available2015-08-02T09:13:25Zen
dc.date.issued2010-09-17en
dc.identifier.issn15237060en
dc.identifier.pmid20734983en
dc.identifier.doi10.1021/ol1016383en
dc.identifier.urihttp://hdl.handle.net/10754/561523en
dc.description.abstractN-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)3/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-β doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes. © 2010 American Chemical Society.en
dc.description.sponsorshipThis work was financially supported by Singapore DSTA DIRP Project (DSTA-NUS-DIRP/2008/03), the NRF Competitive Research Program (R-143-000-360-281), and NUS Young Investigator Award (R-143-000-356-101) to J.W. and a KAUST baseline funding to K.-W.H.en
dc.publisherAmerican Chemical Society (ACS)en
dc.titleN-annulated perylene fused porphyrins with enhanced near-IR absorption and emissionen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentHCLen
dc.identifier.journalOrganic Lettersen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore, Singaporeen
kaust.authorHuang, Kuo-Weien

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