A tristable [2]pseudo[2]rotaxane

Handle URI:
http://hdl.handle.net/10754/561444
Title:
A tristable [2]pseudo[2]rotaxane
Authors:
Trabolsi, Ali; Fahrenbach, Albert C.; Dey, Sanjeev Kumar; Share, Andrew I.; Friedman, Douglas C.; Basu, Subhadeep; Gasa, Travis B.; Khashab, Niveen M. ( 0000-0003-2728-0666 ) ; Saha, Sourav; Aprahamian, Ivan; Khatib, Hussam A.; Flood, Amar H.; Stoddart, Fraser Fraser Raser
Abstract:
A strategy towards increasing the lifetime of the metastable state of a [2]rotaxane incorporating tetrathiafulvalene, 1,5-dioxynaphthalene and bipyridinium (BIPY 2+) is presented. Incorporation of BIPY 2+ served multiple roles as an electrostatic barrier to relaxation, a supramolecular recognition site for bis-1,5-dioxynaphthalene[38]crown-10 macrocycle, and upon reduction a recognition site for the mechanically bonded cyclobis(paraquat-p-phenylene) ring. © The Royal Society of Chemistry 2010.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; Chemical Science Program; Advanced Membranes and Porous Materials Research Center; Smart Hybrid Materials (SHMs) lab
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Issue Date:
2010
DOI:
10.1039/b918321c
Type:
Article
ISSN:
13597345
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Controlled Release and Delivery Laboratory; Chemical Science Program

Full metadata record

DC FieldValue Language
dc.contributor.authorTrabolsi, Alien
dc.contributor.authorFahrenbach, Albert C.en
dc.contributor.authorDey, Sanjeev Kumaren
dc.contributor.authorShare, Andrew I.en
dc.contributor.authorFriedman, Douglas C.en
dc.contributor.authorBasu, Subhadeepen
dc.contributor.authorGasa, Travis B.en
dc.contributor.authorKhashab, Niveen M.en
dc.contributor.authorSaha, Souraven
dc.contributor.authorAprahamian, Ivanen
dc.contributor.authorKhatib, Hussam A.en
dc.contributor.authorFlood, Amar H.en
dc.contributor.authorStoddart, Fraser Fraser Raseren
dc.date.accessioned2015-08-02T09:11:29Zen
dc.date.available2015-08-02T09:11:29Zen
dc.date.issued2010en
dc.identifier.issn13597345en
dc.identifier.doi10.1039/b918321cen
dc.identifier.urihttp://hdl.handle.net/10754/561444en
dc.description.abstractA strategy towards increasing the lifetime of the metastable state of a [2]rotaxane incorporating tetrathiafulvalene, 1,5-dioxynaphthalene and bipyridinium (BIPY 2+) is presented. Incorporation of BIPY 2+ served multiple roles as an electrostatic barrier to relaxation, a supramolecular recognition site for bis-1,5-dioxynaphthalene[38]crown-10 macrocycle, and upon reduction a recognition site for the mechanically bonded cyclobis(paraquat-p-phenylene) ring. © The Royal Society of Chemistry 2010.en
dc.publisherRoyal Society of Chemistryen
dc.titleA tristable [2]pseudo[2]rotaxaneen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentChemical Science Programen
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentSmart Hybrid Materials (SHMs) laben
dc.identifier.journalChemical Communicationsen
dc.contributor.institutionDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60202, United Statesen
dc.contributor.institutionDepartment of Chemistry, Indiana University, 800 East Kirkwood Avenue, Bloomington, IN 47405-7102, United Statesen
dc.contributor.institutionDepartment of Chemistry, Florida State University, 600 W. College Avenue, Tallahassee, FL 32306, United Statesen
dc.contributor.institutionDepartment of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH 03755, United Statesen
kaust.authorTrabolsi, Alien
kaust.authorKhashab, Niveen M.en
kaust.authorKhatib, Hussam A.en
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