Pro-aromatic Bisphenaleno-thieno[3,2-b]thiophene versus Anti-aromatic Bisindeno-thieno[3,2-b]thiophene: Different Ground- state Properties and Applications for Field-effect Transistors

Handle URI:
http://hdl.handle.net/10754/559599
Title:
Pro-aromatic Bisphenaleno-thieno[3,2-b]thiophene versus Anti-aromatic Bisindeno-thieno[3,2-b]thiophene: Different Ground- state Properties and Applications for Field-effect Transistors
Authors:
Shi, Xueliang; Lee, Sangsu; Son, Minjung; Zheng, Bin; Chang, Jingjing; Jing, Linzhi; Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Kim, Dongho; Chi, Chunyan
Abstract:
A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS. X-ray crystallographic analysis of BPT-TIPS disclosed an ordered 3D packing via close π-π interactions and field-effect hole mobility of 0.26 cm2V-1s-1 was obtained.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Pro-aromatic Bisphenaleno-thieno[3,2-b]thiophene versus Anti-aromatic Bisindeno-thieno[3,2-b]thiophene: Different Ground- state Properties and Applications for Field-effect Transistors 2015 Chem. Commun.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Chem. Commun.
Issue Date:
6-Jul-2015
DOI:
10.1039/C5CC04243G
Type:
Article
ISSN:
1359-7345; 1364-548X
Is Supplemented By:
Shi, X., Lee, S., Son, M., Zheng, B., Chang, J., Jing, L., … Chi, C. (2015). CCDC 1055932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc14fsbp; DOI:10.5517/cc14fsbp; HANDLE:http://hdl.handle.net/10754/624424
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC04243G
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorShi, Xueliangen
dc.contributor.authorLee, Sangsuen
dc.contributor.authorSon, Minjungen
dc.contributor.authorZheng, Binen
dc.contributor.authorChang, Jingjingen
dc.contributor.authorJing, Linzhien
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorKim, Donghoen
dc.contributor.authorChi, Chunyanen
dc.date.accessioned2015-07-12T09:09:04Zen
dc.date.available2015-07-12T09:09:04Zen
dc.date.issued2015-07-06en
dc.identifier.citationPro-aromatic Bisphenaleno-thieno[3,2-b]thiophene versus Anti-aromatic Bisindeno-thieno[3,2-b]thiophene: Different Ground- state Properties and Applications for Field-effect Transistors 2015 Chem. Commun.en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.doi10.1039/C5CC04243Gen
dc.identifier.urihttp://hdl.handle.net/10754/559599en
dc.description.abstractA pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS. X-ray crystallographic analysis of BPT-TIPS disclosed an ordered 3D packing via close π-π interactions and field-effect hole mobility of 0.26 cm2V-1s-1 was obtained.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC04243Gen
dc.rightsArchived with thanks to Chem. Commun.en
dc.titlePro-aromatic Bisphenaleno-thieno[3,2-b]thiophene versus Anti-aromatic Bisindeno-thieno[3,2-b]thiophene: Different Ground- state Properties and Applications for Field-effect Transistorsen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalChem. Commun.en
dc.eprint.versionPost-printen
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543en
dc.contributor.institutionSpectroscopy Laboratory for Functional π‐ Electronic Systems and Department of Chemistry, Yonsei University, Seoul 120 ‐ 749, Koreaen
kaust.authorZheng, Binen
kaust.authorHuang, Kuo-Weien
dc.relation.isSupplementedByShi, X., Lee, S., Son, M., Zheng, B., Chang, J., Jing, L., … Chi, C. (2015). CCDC 1055932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc14fsbpen
dc.relation.isSupplementedByDOI:10.5517/cc14fsbpen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624424en
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