Synthesis of core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s by electrostatic self-assembly and covalent fixation (ESA–CF) protocol

Handle URI:
http://hdl.handle.net/10754/556536
Title:
Synthesis of core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s by electrostatic self-assembly and covalent fixation (ESA–CF) protocol
Authors:
Fujiwara, Susumu; Yamamoto, Takuya; Tezuka, Yasuyuki; Habuchi, Satoshi ( 0000-0002-6663-2807 )
Abstract:
A pair of four-armed star and dicyclic 8-shaped poly(tetrahydrofuran)s, poly(THF)s, possessing a perylene diimide group at the core position (Ia and Ib, respectively) were synthesized by means of an electrostatic self-assembly and covalent fixation (ESA–CF) protocol. Mono- and bifunctional poly(THF)s having N-phenylpiperidinium salt end groups accompanying a perylene diimide tetracarboxylate as a counteranion were prepared by the ion-exchange reaction, and the subsequent covalent conversion by reflux in toluene afforded the corresponding core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s, (Ia and Ib, respectively) for the use of single-molecule fluorescence microscopy measurements.
KAUST Department:
Biological and Environmental Sciences and Engineering (BESE) Division
Citation:
Synthesis of core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s by electrostatic self-assembly and covalent fixation (ESA–CF) protocol 2014, 80:3 Reactive and Functional Polymers
Journal:
Reactive and Functional Polymers
Issue Date:
7-Dec-2013
DOI:
10.1016/j.reactfunctpolym.2013.11.007
Type:
Article
ISSN:
13815148
Sponsors:
This work was supported partly by Yazaki Memorial Foundation for Science and Technology (T.Y.) and KAKENHI (23685022 T.Y. and 23350050 Y.T.)
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S1381514813002502
Appears in Collections:
Articles; Biological and Environmental Sciences and Engineering (BESE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorFujiwara, Susumuen
dc.contributor.authorYamamoto, Takuyaen
dc.contributor.authorTezuka, Yasuyukien
dc.contributor.authorHabuchi, Satoshien
dc.date.accessioned2015-06-07T21:46:14Zen
dc.date.available2015-06-07T21:46:14Zen
dc.date.issued2013-12-07en
dc.identifier.citationSynthesis of core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s by electrostatic self-assembly and covalent fixation (ESA–CF) protocol 2014, 80:3 Reactive and Functional Polymersen
dc.identifier.issn13815148en
dc.identifier.doi10.1016/j.reactfunctpolym.2013.11.007en
dc.identifier.urihttp://hdl.handle.net/10754/556536en
dc.description.abstractA pair of four-armed star and dicyclic 8-shaped poly(tetrahydrofuran)s, poly(THF)s, possessing a perylene diimide group at the core position (Ia and Ib, respectively) were synthesized by means of an electrostatic self-assembly and covalent fixation (ESA–CF) protocol. Mono- and bifunctional poly(THF)s having N-phenylpiperidinium salt end groups accompanying a perylene diimide tetracarboxylate as a counteranion were prepared by the ion-exchange reaction, and the subsequent covalent conversion by reflux in toluene afforded the corresponding core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s, (Ia and Ib, respectively) for the use of single-molecule fluorescence microscopy measurements.en
dc.description.sponsorshipThis work was supported partly by Yazaki Memorial Foundation for Science and Technology (T.Y.) and KAKENHI (23685022 T.Y. and 23350050 Y.T.)en
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S1381514813002502en
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Reactive and Functional Polymers. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Reactive and Functional Polymers, 7 December 2013. DOI: 10.1016/j.reactfunctpolym.2013.11.007en
dc.subjectcyclic polymeren
dc.subject8-shaped polymeren
dc.subjectESA-CFen
dc.subjectperylene diimideen
dc.subjectpoly(THF)en
dc.titleSynthesis of core-fluorescent four-armed star and dicyclic 8-shaped poly(THF)s by electrostatic self-assembly and covalent fixation (ESA–CF) protocolen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Divisionen
dc.identifier.journalReactive and Functional Polymersen
dc.eprint.versionPost-printen
dc.contributor.institutionDepartment of Organic and Polymeric Materials, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japanen
kaust.authorHabuchi, Satoshien
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