Nuclear Magnetic Resonance Study of Nanoscale Ionic Materials

Handle URI:
http://hdl.handle.net/10754/555770
Title:
Nuclear Magnetic Resonance Study of Nanoscale Ionic Materials
Authors:
Oommen, Joanna Mary; Hussain, Muhammad Mustafa ( 0000-0003-3279-0441 ) ; Emwas, Abdul-Hamid M.; Agarwal, Praveen; Archer, Lynden A.
Abstract:
Nanoscale ionic materials (NIMs) are a new class of nanomaterials that exhibit interesting properties including negligible vapor pressures and tunable physical states, among others. In this study, we analyzed the temperature-wise performance of NIMs using nuclear magnetic resonance (NMR) spectroscopy. NIMs are relatively stable over a temperature range from 300 to 383 K, rendering them usable in high temperature applications. We confirmed the presence of covalent bonds between the SiO2 core and the sulfonate group and determined relative concentrations of aromatic and aliphatic hydrocarbons. These findings serve as first hand proof-of-concept for the usefulness of NMR analyses in further studies on the diffusive properties of NIMs. © 2010 The Electrochemical Society.
KAUST Department:
Nuclear Magnetic Resonance Core Lab
Citation:
Nuclear Magnetic Resonance Study of Nanoscale Ionic Materials 2010, 13 (11):K87 Electrochemical and Solid-State Letters
Journal:
Electrochemical and Solid-State Letters
Issue Date:
13-Aug-2010
DOI:
10.1149/1.3477935
Type:
Article
ISSN:
10990062
Additional Links:
http://esl.ecsdl.org/cgi/doi/10.1149/1.3477935
Appears in Collections:
Articles

Full metadata record

DC FieldValue Language
dc.contributor.authorOommen, Joanna Maryen
dc.contributor.authorHussain, Muhammad Mustafaen
dc.contributor.authorEmwas, Abdul-Hamid M.en
dc.contributor.authorAgarwal, Praveenen
dc.contributor.authorArcher, Lynden A.en
dc.date.accessioned2015-05-26T07:30:29Zen
dc.date.available2015-05-26T07:30:29Zen
dc.date.issued2010-08-13en
dc.identifier.citationNuclear Magnetic Resonance Study of Nanoscale Ionic Materials 2010, 13 (11):K87 Electrochemical and Solid-State Lettersen
dc.identifier.issn10990062en
dc.identifier.doi10.1149/1.3477935en
dc.identifier.urihttp://hdl.handle.net/10754/555770en
dc.description.abstractNanoscale ionic materials (NIMs) are a new class of nanomaterials that exhibit interesting properties including negligible vapor pressures and tunable physical states, among others. In this study, we analyzed the temperature-wise performance of NIMs using nuclear magnetic resonance (NMR) spectroscopy. NIMs are relatively stable over a temperature range from 300 to 383 K, rendering them usable in high temperature applications. We confirmed the presence of covalent bonds between the SiO2 core and the sulfonate group and determined relative concentrations of aromatic and aliphatic hydrocarbons. These findings serve as first hand proof-of-concept for the usefulness of NMR analyses in further studies on the diffusive properties of NIMs. © 2010 The Electrochemical Society.en
dc.relation.urlhttp://esl.ecsdl.org/cgi/doi/10.1149/1.3477935en
dc.rightsArchived with thanks to Electrochemical and Solid-State Letters © 2010 ECS - The Electrochemical Societyen
dc.subjectbonds (chemical)en
dc.subjectnanostructured materialsen
dc.subjectnuclear magnetic resonanceen
dc.subjectorganic compoundsen
dc.subjectsilicon compoundsen
dc.titleNuclear Magnetic Resonance Study of Nanoscale Ionic Materialsen
dc.typeArticleen
dc.contributor.departmentNuclear Magnetic Resonance Core Laben
dc.identifier.journalElectrochemical and Solid-State Lettersen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionIntegrated Nanotechnology Faben
dc.contributor.institutionSchool of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York 14853-5201, USAen
kaust.authorHussain, Muhammad Mustafaen
kaust.authorEmwas, Abdul-Hamid M.en
kaust.authorOommen, Joanna Maryen
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