High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes

Handle URI:
http://hdl.handle.net/10754/552754
Title:
High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes
Authors:
Bouhrara, M.; Saih, Y.; Wågberg, T.; Goze-Bac, C.; Abou-Hamad, E.
Abstract:
We present 13 C high-resolution magic-angle-turning (MAT) and magic angle spinning nuclear magnetic resonance data of Cs and Rb intercalated single walled carbon nanotubes. We find two distinct phases at different intercalation levels. A simple charge transfer is applicable at low intercalation level. The new phase at high intercalation level is accompanied by a hybridization of alkali (s) orbitals with the carbon (sp2) orbitals of the single walled nanotubes, which indicate bundle surface sites is the most probable alkali site.
KAUST Department:
KAUST Catalysis Center (KCC)
Citation:
High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes 2011, 110 (5):054306 Journal of Applied Physics
Publisher:
AIP Publishing
Journal:
Journal of Applied Physics
Issue Date:
6-Sep-2011
DOI:
10.1063/1.3631052
Type:
Article
ISSN:
00218979
Additional Links:
http://scitation.aip.org/content/aip/journal/jap/110/5/10.1063/1.3631052
Appears in Collections:
Articles; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorBouhrara, M.en
dc.contributor.authorSaih, Y.en
dc.contributor.authorWågberg, T.en
dc.contributor.authorGoze-Bac, C.en
dc.contributor.authorAbou-Hamad, E.en
dc.date.accessioned2015-05-14T07:03:19Zen
dc.date.available2015-05-14T07:03:19Zen
dc.date.issued2011-09-06en
dc.identifier.citationHigh-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes 2011, 110 (5):054306 Journal of Applied Physicsen
dc.identifier.issn00218979en
dc.identifier.doi10.1063/1.3631052en
dc.identifier.urihttp://hdl.handle.net/10754/552754en
dc.description.abstractWe present 13 C high-resolution magic-angle-turning (MAT) and magic angle spinning nuclear magnetic resonance data of Cs and Rb intercalated single walled carbon nanotubes. We find two distinct phases at different intercalation levels. A simple charge transfer is applicable at low intercalation level. The new phase at high intercalation level is accompanied by a hybridization of alkali (s) orbitals with the carbon (sp2) orbitals of the single walled nanotubes, which indicate bundle surface sites is the most probable alkali site.en
dc.publisherAIP Publishingen
dc.relation.urlhttp://scitation.aip.org/content/aip/journal/jap/110/5/10.1063/1.3631052en
dc.rightsArchived with thanks to Journal of Applied Physicsen
dc.titleHigh-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubesen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalJournal of Applied Physicsen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionDepartment of Physics, Umeå University, 901 87 Umeå, Swedenen
dc.contributor.institutionLCVN, Universitè Montpellier II, Place E. Bataillon, 34095 Montpellier, Franceen
kaust.authorBouhrara, Mohameden
kaust.authorSaih, Youssefen
kaust.authorAbou-Hamad, Edyen
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