Crystal structure of tri­chlorido­(4'-ferrocenyl-2,2':6',2''-terpyridine-[kappa]3N,N',N'')iridium(III) aceto­nitrile disolvate

Handle URI:
http://hdl.handle.net/10754/552283
Title:
Crystal structure of tri­chlorido­(4'-ferrocenyl-2,2':6',2''-terpyridine-[kappa]3N,N',N'')iridium(III) aceto­nitrile disolvate
Authors:
Davaasuren, Bambar ( 0000-0002-0270-3426 ) ; Padhy, Harihara; Rothenberger, Alexander
Abstract:
In the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central IrIII atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4'-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol­ecules are stacked in rows parallel to [001], with the aceto­nitrile solvent mol­ecules situated between the rows. An extensive network of intra- and inter­molecular C-H...Cl inter­actions is present, stabilizing the three-dimensional structure.
KAUST Department:
Physical Sciences and Engineering (PSE) Division
Citation:
Crystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ 3 N , N ′, N ′′)iridium(III) acetonitrile disolvate 2015, 71 (3):m69 Acta Crystallographica Section E Crystallographic Communications
Journal:
Acta Crystallographica Section E Crystallographic Communications
Issue Date:
25-Feb-2015
DOI:
10.1107/S2056989015003473
PubMed ID:
25844213
PubMed Central ID:
PMC4350693
Type:
Article
ISSN:
2056-9890
Additional Links:
http://scripts.iucr.org/cgi-bin/paper?S2056989015003473
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division

Full metadata record

DC FieldValue Language
dc.contributor.authorDavaasuren, Bambaren
dc.contributor.authorPadhy, Hariharaen
dc.contributor.authorRothenberger, Alexanderen
dc.date.accessioned2015-05-05T08:51:19Zen
dc.date.available2015-05-05T08:51:19Zen
dc.date.issued2015-02-25en
dc.identifier.citationCrystal structure of trichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ 3 N , N ′, N ′′)iridium(III) acetonitrile disolvate 2015, 71 (3):m69 Acta Crystallographica Section E Crystallographic Communicationsen
dc.identifier.issn2056-9890en
dc.identifier.pmid25844213en
dc.identifier.doi10.1107/S2056989015003473en
dc.identifier.urihttp://hdl.handle.net/10754/552283en
dc.description.abstractIn the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central IrIII atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4'-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol­ecules are stacked in rows parallel to [001], with the aceto­nitrile solvent mol­ecules situated between the rows. An extensive network of intra- and inter­molecular C-H...Cl inter­actions is present, stabilizing the three-dimensional structure.en
dc.relation.urlhttp://scripts.iucr.org/cgi-bin/paper?S2056989015003473en
dc.rightsArchived with thanks to Acta Crystallographica Section E Crystallographic Communicationsen
dc.subjectcrystal structureen
dc.subjectiridiumen
dc.subject4'-ferrocenyl-2,2':6',2''-terpyridineen
dc.titleCrystal structure of tri­chlorido­(4'-ferrocenyl-2,2':6',2''-terpyridine-[kappa]3N,N',N'')iridium(III) aceto­nitrile disolvateen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalActa Crystallographica Section E Crystallographic Communicationsen
dc.identifier.pmcidPMC4350693en
dc.eprint.versionPublisher's Version/PDFen
kaust.authorDavaasuren, Bambaren
kaust.authorPadhy, Hariharaen
kaust.authorRothenberger, Alexanderen
All Items in KAUST are protected by copyright, with all rights reserved, unless otherwise indicated.